Question

In: Chemistry

True or False 1. Zaitzeff's rule is usefull for predicting the regiochemistry of electrophilic addition reaction...

True or False

1. Zaitzeff's rule is usefull for predicting the regiochemistry of electrophilic addition reaction ?

2. Markovnikov's Rule is usefull for predicting the regiochemstry  of electrophilic addition reaction ?

3. A Alkene bromination reaction is an example of an syn addition ?

4.A Hydroboration-Oxidation reaction is an example of an anti-addition ?

5. Carbocations can combine with a nucleophile, eliminate, or rearrange ?

6. A steroespecfic reaction will prdouce only a certain set stereoisomoers due to the reaction mechanisim. ?

Solutions

Expert Solution

a) True

Zaitsev's rule (or Saytzeff rule, Saytzev rule) is an empirical rule for predicting the favored alkene product in elimination reactions. The alkene formed in greatest amount is the one that corresponds to removal of the hydrogen from the β-carbon having the fewest hydrogen substituents

b) false

Markovnikov's rule describes the outcome of some addition reactions but not electrophilic adition reaction. the rule can be stated that the hydrogen atom is added to the carbon with the greatest number of hydrogen atoms while the X component is added to the carbon with the least number of hydrogen atoms.

c) true

Syn addition is the addition of two substituents to the same side of a double bond or triple bond, resulting in a decrease in bond order but an increase in number of substituents.

d) true

hydroboration–oxidation reaction is a two-step organic reaction that converts an alkene into a neutral alcohol by the net addition of water across the double bond. . Hydroboration–oxidation is an anti-Markovnikov reaction, with the hydroxyl group attaching to the less-substituted carbon.

e) true

carbocation can combine with a nucleophile, eliminate, or rearrange

f) false

stereospecificity is the property of a reaction mechanism that leads to different stereoisomeric reaction products from different stereoisomeric reactants, or which operates on only one (or a subset) of the stereoisomers.


Related Solutions

What is the difference between: acid-base oxidation-reduction nucleophilic substitution elimination electrophilic addition nucleophilic addition electrophilic aromatic...
What is the difference between: acid-base oxidation-reduction nucleophilic substitution elimination electrophilic addition nucleophilic addition electrophilic aromatic substitution If you can provide an example, that would be great :)
True or False? Explain. 1.     T / F         The specificity rule says that tariffs are...
True or False? Explain. 1.     T / F         The specificity rule says that tariffs are usually not the best way of curing distortions in a country’s economy. 2.     T / F         National defense and national pride arguments for protection are basically second‑best. 3.     T / F         If “learning by doing” means that more production now translates into lower costs later, the best policy is a protective tariff. 4.     T / F         “Learning by doing” is what...
alkynes can be hydrated in the presence of acid and HgSO4 by electrophilic addition of the...
alkynes can be hydrated in the presence of acid and HgSO4 by electrophilic addition of the molecule of water to the triple bond.The reaction proceedes by way of carbocation intermediate. Hydration of acetylene produces acetaldehyde. Outline the steps that occur in this transformation
True or False for the following questions...... 1) The following reaction is spontaneous at all temperatures....
True or False for the following questions...... 1) The following reaction is spontaneous at all temperatures. 2NO2(g) --> N2(g) + 2O2(g) ∆H = -123 kJ 2) The following reaction is spontaneous at all temperatures. 3O2(g) --> 2O3(g) ∆H = +423 kJ 3) If the following reaction takes place at 300 K, the reaction is spontaneous at 300 K. N2(g)  + 3H2(g) -->   2NH3(g) ∆H = -90 kJ ∆S for N2(g) = 192 J/molK; ∆S for H2(g) = 131 J/molK; ∆S for...
True or False? Please, explain. (a) Addition of a solute at constant T and P to...
True or False? Please, explain. (a) Addition of a solute at constant T and P to a pure solvent A always decreases µA. (b) The system’s temperature remains constant as pure water freezes at constant pressure. (c) The system’s temperature remains constant as an aqueous solution of sucrose freezes at constant pressure. (d) If a solute partly dimerizes in a solvent, the freezing-point depression is less than it would be if the solute did not dimerize. (e) The osmotic pressure...
True or False? Please, explain. (a) Addition of a solute at constant T and P to...
True or False? Please, explain. (a) Addition of a solute at constant T and P to a solution containing solvent A always decreases μA. (b) Addition of a nonvolatile solute at constant T to a pure solvent always lowers the vapor pressure. (c) For a binary two-phase system, the closer the point on a tie line is to a phase, the more of that phase is present. (d) A system at equilibrium with substances i and k present in phase...
What are the electrophile and nucleophilic in the electrophilic aromatic substitution reaction.
What are the electrophile and nucleophilic in the electrophilic aromatic substitution reaction.
True and False True/False Write True or False before the statement. 1. Gypsum is the brand...
True and False True/False Write True or False before the statement. 1. Gypsum is the brand name for sheetrock. 2. Coreboards and liner boards come in 2-foot widths. 3. Adhesives are not used for bonding gypsum board directly to supports. 4. Supplemental fasteners should be used with contact adhesives. 5. Gypsum panels are applied first to ceilings and then to the walls. 6. The floating angle method of drywall application omits fasteners in the corner intersection of the ceilings and...
1.The fundamental rule of the balance sheet is assets equals liabilities plus owners’ equity. True False...
1.The fundamental rule of the balance sheet is assets equals liabilities plus owners’ equity. True False 2.Owners’ equity are the things a business owns, such as cash, inventory, and money owed from customers. True False 3.The cumulative profits of the business since inception are known as retained earnings. True False 4.Assets and liabilities on a balance sheet are always presented at current market value. True False 5.The main sections of a balance sheet are: Assets, liabilities, and net profits Assets,...
compare a nucleophilic addition to a electrophilic atomatic substitution. how are the mechanisms alike and how...
compare a nucleophilic addition to a electrophilic atomatic substitution. how are the mechanisms alike and how are they different?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT