Question

In: Chemistry

Part A Draw the alcohol and the alkyl halide that would be used to synthesize cyclohexyl...

Part A Draw the alcohol and the alkyl halide that would be used to synthesize cyclohexyl propyl ether by Williamson ether synthesis.

Draw the molecules on the canvas by choosing buttons from the Tools (for bonds and charges), Atoms, and Templates toolbars.

Part B

Draw the alcohol and the alkyl halide that would be used to synthesize isopropyl methyl ether by Williamson ether synthesis.

Part C

Draw the alcohol and the alkyl halide that would be used to synthesize 1-methoxy-4-nitrobenzene by Williamson ether synthesis.

.

Part D

Draw the alcohol and the alkyl halide that would be used to synthesize ethyl n-propyl ether (two ways) by Williamson ether synthesis.

Part E

Draw the alcohol and the alkyl halide that would be used to synthesize benzyl tert-butyl ether (benzyl = Ph?CH2?) by Williamson ether synthesis.

Solutions

Expert Solution


Related Solutions

Choose all possible reagents for the reaction of a primary alcohol to alkyl halide and, for...
Choose all possible reagents for the reaction of a primary alcohol to alkyl halide and, for part B, choose all possible reagents for a primary alcohol to alkene reaction A) HBr with heat, thionyl chloride with base, HCl with heat, PBr3, concentrated sulfuric acid with heat, HF with heat, NaOH with heat B)concentrated sulfuric acid with heat, HCl with heat, HF with heat, NaOH with heat, PBr3, thionyl chloride with base, HBr with heat
In friedel-crafts alkylation of benzene with an alkyl halide and AlCl3: 1. In terms of intermediate...
In friedel-crafts alkylation of benzene with an alkyl halide and AlCl3: 1. In terms of intermediate and product stabilities explain why the ortho and para isomers would be favored under kinetic conditions and why the meta isomer would be favored under thermodyanmic conditions? 2. What function does the nitromethane serve in the kinetic reaction? 3. What reactants would you employ for the preparation of the following compounds by reactions of the Friedel-crafts type? - a. diphenylmethane - b. 4-bromophenyl phenyl...
how the leaving group affect the behavior of the alkyl halide in mixture of NaI/ Acetone...
how the leaving group affect the behavior of the alkyl halide in mixture of NaI/ Acetone and in mixture of AgNO3/ Ethanol?
How many of the following responses are true? 1. A primary alkyl halide will tend to...
How many of the following responses are true? 1. A primary alkyl halide will tend to react through an SN2 mechanism because there is little hindrance to backside attack and a primary carbocation is not very stable 2. 3-bromo-3-methylpentane will undergo substitution through an SN2 mechanism 3. If R-2-bromopentane is allowed to react with OH- the product will be S-2-pentanol 4. SN1 leads to a racemization of sterechemistry due to the nucleophile attacking from the backside and the leaving group...
The Gabriel synthesis transforms an alkyl halide into a primary amine via a two-step process.
The Gabriel synthesis transforms an alkyl halide into a primary amine via a two-step process. Follow the directions below to draw the initial mechanism and final products. Draw curved arrows to the next step. Draw the missing nonbonding electrons, charge and curved arrows. The first three steps are correct. I am unsure about how to complete the final step. 
Fill in the boxes with the missing alkyl halide, appropriate nucleophile, or substitution product. Show stereochemistry...
Fill in the boxes with the missing alkyl halide, appropriate nucleophile, or substitution product. Show stereochemistry on the product when applicable. Ph = benzene ring, Et = ethyl. https://puu.sh/xUr4f/c0595fcff7.png
Carboxylic acids can be made by the hydrolysis of nitriles, which in turn can be made from an alkyl halide.
Carboxylic acids can be made by the hydrolysis of nitriles, which in turn can be made from an alkyl halide. Draw the structures of a starting alkyl bromide and the intermediate nitrile that would be used in the synthesis of 3-methylbutanoic acid (isovaleric acid) Do not show free ions.
Percent yield of alkyl halide (Show all calculations for limiting reactant, theoretical yield and percent yield.)...
Percent yield of alkyl halide (Show all calculations for limiting reactant, theoretical yield and percent yield.) Note I have 1.746g of product obatined of pure alkyl halide Also my unkown that i chose for this experiment was 3-methyl-1-butanol---- I started with 18.996g---15.281g after reflux-- 14.993g after IR spectroscopy
4A- under polar aprotic (NaI, acetone) conditions predict the outcomes of the first 6 alkyl halide...
4A- under polar aprotic (NaI, acetone) conditions predict the outcomes of the first 6 alkyl halide reactions 4B- under polar protic conditions (EtOH, Ag) predict the outcomes of the first 6 alkyl halide reactions (hint: hand draw the mechanisms, see if they make sense) 1) 1-Bromobutane 2) 2-Bromobutane 3) 2-Bromo-2-methylpropane 4) bromobenzene 5) 1-chlorobutane 6) 2-Chlorbutane 7) 2-Chloro-2-methylpropane 8) 1-Chloro-2-butene
Percent yield of alkyl halide (Show all calculations for limiting reactant, theoretical yield and percent yield.)...
Percent yield of alkyl halide (Show all calculations for limiting reactant, theoretical yield and percent yield.) Given: R-CH2OH +NaBr +H2SO4---------> R-CH2BR +H2O+ NaHSO4 - started with - unkown alcohol: 3-methyl-1-butanol (18.996 g) started with, -NaBr ( 10.509g) used -H2SO4 (25 mL of 8.7M) -My alkyl halide is 1-bromo-3- methylbutane -H2O -NaHSO4 Note! I ended with 1.746g of the alkyl halide is 1-bromo-3- methylbutane
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT