In: Chemistry
Predict the major products of the following reactions, including stereochemistry where appropriate.
(a) (R)-butan-2-ol + TsCl in pryidine | (b) (S)-2-butyl tosylate + NaBr |
(c) cyclooctanol + NaOCl/ HOAc | (d) cyclopentylmehanol + CrO3 · pyridine · HCl |
(e) cyclopentylmethanol +Na2Cr2O7/ H2SO4 | (f) cyclopentanol + HCl/ZnCl2 |
(g) n-butanol + HBr | (h) cycloocatylmethanol + CH3CH2MgBr |
(i) potassium tert-butoxide + methyl iodide | (j) sodium methoxide + tert-butyl iodide |
(k) cyclopentanol + H2SO4/ heat | (l) product from (k) + OsO4/H2O2, then HIO4 |
(m) sodium ethoxide + 1-bromobutane | (n) sodium ethoxide + 2-methyl-2-bromobutane |
(o) octan-1-ol + DMSO + oxalyl chloride | (p) 4-cyclopentylhexan-1-ol + DMP reagent |