28. The mechanism of a reaction is shown below: OCl-(aq) + H2O(l) <--> HOCl(aq) + OH-(aq)...

28. The mechanism of a reaction is shown below:

OCl^-_(aq) + H₂O_(l) <--> HOCl_(aq) + OH^-_(aq) (fast)

HOCl_(aq)₎ + I^-_(aq) --> HOI_(aq) + Cl^-_(aq)(slow)

HOl^-_(aq)₎ + OH^-_(aq) ---> H₂O_(l) + OI^- (fast)

a) What is the overall reaction? b) What are the intermediates? c)Which is the rate determining step? d) What is the rate law? e) What is the k value equal to in the rate law? (in terms of k values, not numerically)

Need all parts answered, please show all work and explanations! Thank you in advance!

Solutions

Expert Solution

queen_honey_blossom answered 1 year ago

Next > < Previous

Related Solutions

The reaction of methylacetate with water is shown below: CH3CO2CH3 (aq) + H2O (l) ? CH3CO2H...

The reaction of methylacetate with water is shown below: CH3CO2CH3 (aq) + H2O (l) ? CH3CO2H (aq) + CH3OH (aq) The rate of the reaction is given by the following rate law: rate = k[H+][CH3CO2CH3] Consider one liter of solution that is 0.15 M CH3CO2CH3 (aq) and 0.015 M H+ (aq) at 25?C (a) For each change listed below state whether the rate of reaction increase, decreases or remains the same. Why? (i) methylacetate (CH3CO2CH3) is added to the solution...

The enthalpy of reaction for HCN(aq) + OH-(aq) -> CN-(aq) + H2O(l) is -12.1 kJ/mol. Assuming...

The enthalpy of reaction for HCN(aq) + OH-(aq) -> CN-(aq) + H2O(l) is -12.1 kJ/mol. Assuming that the correct enthalpy of reaction of the experiment is -54.0 kJ/mol, calculate the enthalpy change for the ionization of HCN: HCN(aq) -> H+(aq) + CN-(aq) Be sure to report your answer to the correct number of significant figures. ΔH = ____ kJ/mol

What salt is produced in each of the following neutralization reactions? HNO3(aq)+KOH(aq)→H2O(l)+? HNO3(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+KOH(aq)→H2O(l)+? Drag...

What salt is produced in each of the following neutralization reactions? HNO3(aq)+KOH(aq)→H2O(l)+? HNO3(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+KOH(aq)→H2O(l)+? Drag the appropriate items to their respective reaction. K2NO3, KNO3, Ca(NO3)2, CaNO3, CaCl, CaCl2, KCl2, KCl Reaction A- Reaction B- Reaction C- Reaction D – Not a product -

Part B What salt is produced in each of the following neutralization reactions? HNO3(aq)+KOH(aq)→H2O(l)+? HNO3(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+Ca(OH)2(aq)→H2O(l)+?...

Part B What salt is produced in each of the following neutralization reactions? HNO3(aq)+KOH(aq)→H2O(l)+? HNO3(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+Ca(OH)2(aq)→H2O(l)+? HCl(aq)+KOH(aq)→H2O(l)+? Drag the appropriate items to their respective bins. Part C Which substances are always produced in an acid-base neutralization reaction? Check all that apply. Check all that apply. a base water an acid a gas a salt

What is the equilibrium constant expression for the following reaction: C5H5NH(aq) + H2O(l)↔C5H5NH2+(aq)+OH−(aq) Choose from the...

What is the equilibrium constant expression for the following reaction: C5H5NH(aq) + H2O(l)↔C5H5NH2+(aq)+OH−(aq) Choose from the list below and enter the letters alphabetical order. (e.g. For an equilibrium constant of [OH-]-1eq[H2O]eq enter AH.) A) [H2O]eq E) [H2O]-1eq I) (XPbI2)2eq B) [C5H5NH]eq F) [C5H5NH]-1eq J) [Pb2+]-2eq C) [C5H5NH2+]eq G) [C5H5NH2+]-1eq K) [I-]-2eq D) [OH-]eq H) [OH-]-1eq L) (XPbI2)-2eq

Consider the ionization of aqueous ammonia: NH3(aq) + H2O(l) ⇌ NH4 + (aq) + OH- (aq)...

Consider the ionization of aqueous ammonia: NH3(aq) + H2O(l) ⇌ NH4 + (aq) + OH- (aq) a)Using the thermodynamic data from the textbook (Appendix C), calculate the values of ∆H°rxn, ∆G°rxn, and ∆S°rxn for this process at 25o C. b)Calculate the value of Kb (with 2 sig figs) at 25o C from the value of ∆G°rxn. c) The value of ∆G°rxn you obtain (if your calculations are correct) must be positive, indicating that the reaction in question is non-spontaneous. Why...

Free chlorine in water distributes between HOCl and OCL^- species according to the following reaction: HOCl...

Free chlorine in water distributes between HOCl and OCL^- species according to the following reaction: HOCl <--> H^+ + OCl^- K=[H^+][OCl^-]/[HOCl] = 10^-7.6 @ 25 degrees C A water has a pH of 7.8, temperature of 25 degrees C, and the total free chlorine (HOCl + OCl^-) = 1.2*10^-4 mole/L. Calculate the concentration of the HOCl species in mg/L.

Classify the reaction Ca(OH)2 (aq) + H2CO3(aq) → CaCO3(s) + 2 H2O(l): a. Acid-Base b. Precipitation...

Classify the reaction Ca(OH)2 (aq) + H2CO3(aq) → CaCO3(s) + 2 H2O(l): a. Acid-Base b. Precipitation c. Both d. Neither Sodium phosphate reacts with calcium chloride. Write the balanced, net ionic equation, and then choose the coefficient associated with the calcium ion in that equation (choose 0 if not present): a. 0 b. 1 c. 2 d. 3 Sulfuric acid reacts with barium hydroxide. Write the balanced, net ionic equation, and then choose the coefficient associated with the hydroxide ion...

Calculate the pH of a 0.19 M CH3NH3+ solution. CH3NH2+(aq) + H2O(l) = CH3NH3+(aq) + OH-(aq)...

Calculate the pH of a 0.19 M CH3NH3+ solution. CH3NH2+(aq) + H2O(l) = CH3NH3+(aq) + OH-(aq) Species, Data CH3NH2, Kb = 3.70x10-4. CH3NH2+, Ka = 2.73x10-11.

a) identify the conjugate acid-base pairs for the following reaction: H2O (aq) + CN- (aq)--->HCN (aq)+OH-...

a) identify the conjugate acid-base pairs for the following reaction: H2O (aq) + CN- (aq)--->HCN (aq)+OH- (aq) b) give the conjugate acid of HSO4- and PO4 -2 c) give the conjugate base of HCLO4 and H3O+

Subjects