In: Chemistry
Enter your answers in scientific
notation.
Carbon dioxide is removed from the atmosphere of space
capsules by reaction with a solid metal hydroxide. The products are
water and the metal carbonate.
(a) Calculate the mass of CO2
that can be removed by reaction with 5.26 kg
of lithium hydroxide.
_____g CO2
(b) How many grams of CO2 can
be removed by 0.11 kg of each of the following:
lithium hydroxide, magnesium hydroxide, and aluminum
hydroxide?
By lithium hydroxide:
____g CO2
By magnesium hydroxide:
_____g CO2
By aluminum hydroxide:
_____g CO2
The metal hydroxide is LiOH
The reaction is
2LiOH + CO2 ---> Li2CO3 + H2O
a) as per given equation 2moles of LiOH (2 X23.95 g) can remove 1 mole of CO2 (44grams)
The mass of LiOH = 5.26Kg = 5260grams
So moles of LiOH = 5260 / 23.95 = 219.62 moles
It will remove moles of CO2 = 0.5 X 219.62 = 109.81 moles
Mass of CO2 = Moles X molecular weight = 109.81 X 44 = 4831.64 grams of CO2
b)
(i)The reaction stoichiometry will be the same
2moles of LiOH (2 X23.95 g) can remove 1 mole of CO2 (44grams)
The mass of LiOH = 0.11Kg = 110 grams
So moles of LiOH = 110 / 23.95 = 4.59 moles
It will remove moles of CO2 = 0.5 X 4.59 = 2.295 moles
Mass of CO2 removed = Moles X molecular weight = 2.295 x 44 = 100.98 grams
(ii) The reaction of Mg(OH)2 with CO2 will be
Mg(OH)2+ CO2 ---> MgCO3 + H2O
One mole of Mg(OH)2 will react with one mole of CO2
The mass of Mg(OH)2 = 0.11Kg = 110 grams
So moles of LiOH = 110 / 58.32 = 1.89moles
It will remove moles of CO2 = 1.89
Mass of CO2 that can be removed = 1.89 X 44 grams = 83.16 grams
(iii) The reaction of Al(OH)3 with CO2 will be
2Al(OH)3+ 3CO2 ---> Al2(CO3)3 + 3H2O
two moles of Al(OH)3 will react with three moles of CO2
The mass of Al(OH)3 = 0.11Kg = 110 grams
So moles of Al(OH)3 = 110 / 78 = 1.41moles
It will remove moles of CO2 = 1.5 X 1.41 = 2.115 moles
Mass of CO2 that can be removed = 2.115 X 44 grams = 93.06 grams