Question

In: Chemistry

Enter your answers in scientific notation. Carbon dioxide is removed from the atmosphere of space capsules...

Enter your answers in scientific notation.

Carbon dioxide is removed from the atmosphere of space capsules by reaction with a solid metal hydroxide. The products are water and the metal carbonate.

(a) Calculate the mass of CO2 that can be removed by reaction with 5.26 kg of lithium hydroxide.


_____g CO2


(b) How many grams of CO2 can be removed by 0.11 kg of each of the following: lithium hydroxide, magnesium hydroxide, and aluminum hydroxide?


By lithium hydroxide:

____g CO2


By magnesium hydroxide:

_____g CO2


By aluminum hydroxide:

_____g CO2

Solutions

Expert Solution

The metal hydroxide is LiOH

The reaction is

2LiOH + CO2 ---> Li2CO3 + H2O

a) as per given equation 2moles of LiOH (2 X23.95 g) can remove 1 mole of CO2 (44grams)

The mass of LiOH = 5.26Kg = 5260grams

So moles of LiOH = 5260 / 23.95 = 219.62 moles

It will remove moles of CO2 = 0.5 X 219.62 = 109.81 moles

Mass of CO2 = Moles X molecular weight = 109.81 X 44 = 4831.64 grams of CO2

b)

(i)The reaction stoichiometry will be the same

2moles of LiOH (2 X23.95 g) can remove 1 mole of CO2 (44grams)

The mass of LiOH = 0.11Kg = 110 grams

So moles of LiOH = 110 / 23.95 = 4.59 moles

It will remove moles of CO2 = 0.5 X 4.59 = 2.295 moles

Mass of CO2 removed = Moles X molecular weight = 2.295 x 44 = 100.98 grams

(ii) The reaction of Mg(OH)2 with CO2 will be

Mg(OH)2+ CO2 ---> MgCO3 + H2O

One mole of Mg(OH)2 will react with one mole of CO2

The mass of Mg(OH)2 = 0.11Kg = 110 grams

So moles of LiOH = 110 / 58.32 = 1.89moles

It will remove moles of CO2 = 1.89

Mass of CO2 that can be removed = 1.89 X 44 grams = 83.16 grams

(iii) The reaction of Al(OH)3 with CO2 will be

2Al(OH)3+ 3CO2 ---> Al2(CO3)3 + 3H2O

two moles of Al(OH)3 will react with three moles of CO2

The mass of Al(OH)3 = 0.11Kg = 110 grams

So moles of Al(OH)3 = 110 / 78 = 1.41moles

It will remove moles of CO2 = 1.5 X 1.41 = 2.115 moles

Mass of CO2 that can be removed = 2.115 X 44 grams = 93.06 grams


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