Question

In: Chemistry

write the oxidation reaction,the reduction reaction, and the cell reaction for the system below: Pt l...

write the oxidation reaction,the reduction reaction, and the cell reaction for the system below:
Pt l H2 (g,p )l HCl (0,030 mol /kg) l AgCl l Ag ,

Solutions

Expert Solution

AgCl(s) +  e Ag(s) + Cl Eo(V) = +0.22233
2 H+ + 2 e H2(g) Eo(V) = 0.0000


here the one which is having higher reduction potential will get reduced first.We have Ag having higher reduction potential so it will get reduced from Ag+ to Ag,whereas H2 will get oxidized

The oxidation reaction which occurs at the anode would be

H2 2H+(aq) + 2e

the reduction which occurs at the cathode would be

AgCl(s) + e Ag(s) + Cl

Overall Cell reaction will be

2AgCl(s) + H2(g) 2Ag(s) + 2H+ (aq) + 2Cl– (aq)


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