Question

In: Chemistry

Nitrate ion is a good oxidizing agent in acidic solution, and silver metal, which does not...

Nitrate ion is a good oxidizing agent in acidic solution, and silver metal, which does not react with HCl (aq), readily reacts with nitric acid, HNO3 (aq). Explain why

Solutions

Expert Solution

Soln) Nitrate ion (NO3^-1) is a good oxidising agent in acidic solution becoz:

i)nitrogen atom in nitrate ion is in its highest oxidation state (+5) so it can be readily reduced further

ii)on reaction of nitric acid with metals causes oxidation of hydrogen to form water which shows its strong oxidising behavior

Silver does not react with HCL because:

i) silver has higher reduction potential than hydrogen and hence it cannot displace hydrogen from acid due to lower reactivity than hydrogen in reactivity series

Silver reacts readily with nitric acid because:

i) nitric acid is strong oxidising agent which readily oxidises non metals,metals ,inorganic and organic substances and itself gets reduced easily.

with hot conc nitric acid :

Ag + 2HNO3 ----------------------------->AgNO3 + NO2 + H2O

with cold dilute nitrc acid :

Ag + HNO3 -------------------------------->AgNO3 + NO + H2O

queen_honey_blossom answered 2 years ago
Next > < Previous

Related Solutions

In acidic solution, the sulfate ion can be used to react with a number of metal...
In acidic solution, the sulfate ion can be used to react with a number of metal ions. One such reaction is SO42−(aq)+Sn2+(aq)→H2SO3(aq)+Sn4+(aq) Since this reaction takes place in acidic solution, H2O(l) and H+(aq) will be involved in the reaction. Places for these species are indicated by the blanks in the following restatement of the equation: SO42−(aq)+Sn2+(aq)+     −−−→H2SO3(aq)+Sn4+(aq)+     −−− What are the coefficients of the reactants and products in the balanced equation above? Remember to include H2O(l) and H+(aq) in the appropriate blanks....
1. You will be given a solution of silver nitrate from which to synthesize silver nanoprisms....
1. You will be given a solution of silver nitrate from which to synthesize silver nanoprisms. The silver in the nanoprisms is Ag0. What do you need to do to the silver to get it into that form? Which would you use to do that: KBr, H2O2, NaBH4, sodium citrate? Why?
Acidic solution In acidic solution, the iodate ion can be used to react with a number...
Acidic solution In acidic solution, the iodate ion can be used to react with a number of metal ions. One such reaction is IO3−(aq)+Sn2+(aq)→I−(aq)+Sn4+(aq) Since this reaction takes place in acidic solution, H2O(l) and H+(aq) will be involved in the reaction. Places for these species are indicated by the blanks in the following restatement of the equation: IO3−(aq)+Sn2+(aq)+ −−−→I−(aq)+Sn4+(aq)+ −−− Part A What are the coefficients of the reactants and products in the balanced equation above? Remember to include H2O(l)...
which is the oxidizing agent? which is the reducing agent? which is being oxidized? which is...
which is the oxidizing agent? which is the reducing agent? which is being oxidized? which is being reduced in the following photosynthesis reaction? 6H20+6CO2+light=>C6H12O2+6O2
which is the oxidizing agent? which is the reducing agent? which is being oxidized? which is...
which is the oxidizing agent? which is the reducing agent? which is being oxidized? which is being reduced in the following photosynthesis reaction? 6H20+6CO2=C6H12O2+6O2
2,Which has greater normality as an oxidizing agent in the presence of acid, a solution containing...
2,Which has greater normality as an oxidizing agent in the presence of acid, a solution containing 0.32g of KMnO4 per 100ml or one containing 0.72g of K2Cr2O7 per 150ml? How many mililiters pf 0.1N stannous salt will 50ml of each of the oxidizing agents react with in the presence of acid to form stannic salt? How many grams of Sn are present in each liter of the stannic salt？
A) Titration of an acidic solution of Na2C2O4 with KMnO4(aq). Which species is the reducing agent?...
A) Titration of an acidic solution of Na2C2O4 with KMnO4(aq). Which species is the reducing agent? Express your answer as an ion. I know the reducing agent is the Na2C2O4 but I need the ION form. B)A voltaic cell utilizes the following reaction: 2Fe3+(aq)+H2(g)→2Fe2+(aq)+2H+(aq) .What is the emf for this cell when [Fe3+]= 3.50 M , PH2= 0.99 atm , [Fe2+]= 1.1×10−3 M , and the pHin both compartments is 4.15? Express your answer using two significant figures. 0.771 V...
Which of the following Cations is the best oxidizing agent and which is the worst? a)...
Which of the following Cations is the best oxidizing agent and which is the worst? a) Pb+2 b) Cr+3 c) Fe+2 d) Sn+2
Consider the reaction between oxalate ion and permanganate ion in acidic solution: ???4 − (??) +...
Consider the reaction between oxalate ion and permanganate ion in acidic solution: ???4 − (??) + ?2?4 2−(??) → ??2+(??) + ??2 (?) a. Balance the reaction in acidic solution b. Determine the standard cell potential of the representative voltaic cell c. Determine the standard free energy change of this reaction d. Determine the cell potential if the pH = 4 and all other solute concentrations were standard.
Consider the reaction between oxalate ion and permanganate ion in acidic solution: ???4 − (??) +...
Consider the reaction between oxalate ion and permanganate ion in acidic solution: ???4 − (??) + ?2?4 2−(??) → ??2+(??) + ??2 (?) a. Balance the reaction in acidic solution b. Determine the standard cell potential of the representative voltaic cell c. Determine the standard free energy change of this reaction d. Determine the cell potential if the pH = 4 and all other solute concentrations were standard.
ADVERTISEMENT
Subjects
ADVERTISEMENT
Latest Questions
ADVERTISEMENT