In: Chemistry
The balanced equation for the combustion of butane is: 2C4H10 +13O2-->8CO2 + 10H2)
If the combustion of 42.0 g of C4H10 produces 103 g of CO2. What is the percent yield of the reaction? (Assume oxygen is in excess.)
solution:
the balanced combustion reaction is
2 C4H10 + 13 O2 -----------------------> 8 CO2 + 10 H2O
The reaction suggests 2 moles of C4H10 in presence of 13 moles of oxygen gives 8 moles of CO2 and 10 moles of water.
since oxygen is excess, C4H10 will be limiting reactant
moles = mass/Molar mass,
molar masses ( g/mole) : C4H10 = 58g/mol, CO2 = 44 g/mol and H2O = 18 g/mol
therefore, Moles of C4H10 = 42 / 58 = 0.724 moles
since 2 mole of C4H10 gives 8 moles of CO2
0.0.724 moles of C4H10 will gives 0.724*(8/2) = 2.89 moles of CO2,
So, mass of CO2 = 2.89*44 = 127.45 gm
Mass of CO2 produced theoretically = 127.45 gm ,
And, actual yield = 103 gm
therefore,
(%)percent yield = (actual yield/theoretical yield) *100
percent yield = 103/127.45 = 80.8%
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