In: Chemistry
Iron-59 has a half-life of 45.1 days. How old is an iron nail if the Fe-59 content is 25% that of a new sample of iron? Show all calculations leading to a solution.
First order kinetics is followed by all radio decay.
First order decay equation is given by,
A= A0e-kt , where A= final activity, A0= initial activity , k=rate constant and t=decay time
Now, the rate constant, k can be determined using the equation of as a function of half life as---
k.t1/2 = 0.693------- equation (1)
Given in the question,
t1/2 =45.1 days
=> k = (0.693 / 45.1) days-1 ----- using equation (1)
=> k =0.0154 days-1
Again,
from first order decay equation we have,
A= A0e-kt
=> ln (A/A0) = -kt
=> t = [ln(A/A0) /-k]
=> t= ln [(25/100) / -0.0154 ] days
=> t= (ln 0.25 ) / -0.0154 days
=> t= -1.386 /-0.0154 days
=> t= 90 days
Thus, the iron nail is 90 days old.