In: Chemistry
What phase-space function is a constant of motion??? Give examples and the equations.
Phase space coordinates means position,velocity or position,momentum.
The phase space is the space of all possible states of a system;
the state of a mechanical system is defined by the constituent
positions p and momenta q. p and q together determine the future
behavior of that system. In other words if you know p and q at time
t you will be able to calculate the p and q at time t+1 using the
theorems of classical mechanics - Hamilton's equations.
To describe the motion of a single particle you will need 6
variables, 3 positions and 3 momenta. You can imagine a 6
dimensional space; three positions and three momenta. Each point in
this 6 dimensional space is a possible description of the
particles' possible states, of course constraint by the laws of
classical mechanics.
If you have N particles to describe the system, you have a
6N-dimensional phase space.
Let's make a simple example. The Pendulum. The Pendulum consists of
a single particle mass that swings in a plane. The pendulum is thus
fully described by one position and one momentum. Its momentum is
zero at the top and maximum at bottom. The position perhaps is
denoted by angle and varies between plus/minus a. If you draw
states p and a in a Cartesian plane coordinate system you will get
an ellipsoid (or if chose adequate coordinates a circle) that fully
describes all possible states of the pendulum.
In quantum mechanics the term phase re-appeared: it refers to the
complex phase of the complex numbers that wave functions take
values in.
In quantum mechanics, the coordinates p and q of
phase space normally become operators in a Hilbert space.
A quantum mechanical state does not necessarily have a well-defined
position or a well-defined momentum (and never can have both
according to Heisenberg's uncertainty principle). The notion of
phase space and of a Hamiltonian H, can be viewed as a crucial link
between what otherwise looks like two very different theories. A
state is now not a point in phase space, but is instead a complex
valued wave function. The Hamiltonian H becomes an operator and
describes the observable quantity.