Question

In: Chemistry

What part of the spectra out provides information about the identity of the compound? Molar Absorptivity,...

What part of the spectra out provides information about the identity of the compound?

Molar Absorptivity, Transmission , Absorbance, Wavelength

What part of the spectra out provides information about the quantity of the compound?

Molar Absorptivity, Transmission , Absorbance, Wavelength

How is the measured quantity, transmittance, related to the calculated quantity, absorbance?

Absorbance = 1/transmittance, Absorbance = e^(transmittance) , Absorbance = transmittance, Absorbance = -log(transmittance)

How is absorbance related to concentration (the symbol α means proportional to)?

Absorbance α concentration, Absorbance α -log(concentration) , Absorbance α e^( concentration), Absorbance α 1/ concentration

Solutions

Expert Solution

1. What part of the spectra out provides information about the identity of the compound?

Answer: Wavelength

Because for a particular chemical species there will be a particular λmax by which one can identify a compound.

Molar absorptivity tells that how a chemical species attenuates lights at a particular wavelength.

Transmittance tells about how much of light is transmitted after passing through a chemical species.

Absorbance tells about the amount of light absorbed by a chemical species.

2. What part of the spectra out provides information about the quantity of the compound?

Answer: Molar absorptivity

Molar absorptivity tells that how a chemical species attenuates lights at a particular wavelength.

3. How is the measured quantity, transmittance, related to the calculated quantity, absorbance?

Answer: Absorbance = -log(transmittance)

A= -log(T)

T= Transmittance

T = P (power of monochromatic light initial) / P0 (Power of monochromatic light after passing through solution)

A= Absorbance

A =logP0/P

A =log(1/T)

A= -log T

4. How is absorbance related to concentration (the symbol α means proportional to)?

Answer: Absorbance α concentration

A= CL ----Beer Lambert's Law

=molar absorptivity coefficient

C= concentration of solution

L = Path length

And hence we can say that

A is directly proportional to the concentration of the solution.


Related Solutions

The following information is to be used for the next two questions. Molar absorptivity data for...
The following information is to be used for the next two questions. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are εCo = 36400 and εNi = 5520 at 510 nm and εCo = 1240 and ε Ni = 17500 at 656 nm. A 0.445-g sample was dissolved and diluted to 250.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance...
The following information is to be used for the next two questions. Molar absorptivity data for...
The following information is to be used for the next two questions. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are εCo = 36400 and εNi = 5520 at 510 nm and εCo = 1240 and ε Ni = 17500 at 656 nm. A 0.583-g sample was dissolved and diluted to 200.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance...
The following information is to be used for the next two questions. Molar absorptivity data for...
The following information is to be used for the next two questions. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are εCo = 36400 and εNi = 5520 at 510 nm and εCo = 1240 and ε Ni = 17500 at 656 nm. A 0.556-g sample was dissolved and diluted to 150.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance...
The following information is to be used for the next two questions. Molar absorptivity data for...
The following information is to be used for the next two questions. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are εCo = 36400 and εNi = 5520 at 510 nm and εCo = 1240 and ε Ni = 17500 at 656 nm. A 0.514-g sample was dissolved and diluted to 150.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance...
The molar absorptivity of a compound at 500 nm wavelength is 252 M-1cm-1. Suppose one prepares...
The molar absorptivity of a compound at 500 nm wavelength is 252 M-1cm-1. Suppose one prepares a solution by dissolving 0.00140 moles of a solute in enough water to make a 500.0 mL solution. What would be the absorbance in a 7 .00 mm pathlength cell? Type answer:  
Find the following information for the compound Na2S: a. What is the molar mass of the...
Find the following information for the compound Na2S: a. What is the molar mass of the compound? b. How many moles of Na+ ions are there in 223g of the compound? c. How many S2- ions/atoms are there in part b? d. If the compound is reacted with Lead(II) nitrate, what are the complete and net ionic equations?
Part A SeO3 Spell out the full name of the compound.
Part A SeO3 Spell out the full name of the compound.
Write out the Accounting Identity of Savings = Investment Make sure to identify each part of...
Write out the Accounting Identity of Savings = Investment Make sure to identify each part of savings and investment What is Odious Debt? (Opinion:) Is the U.S. debt Odious?
1. a. The compound X3Y is 35.0% X. What is the molar mass of Y if...
1. a. The compound X3Y is 35.0% X. What is the molar mass of Y if the molar mass of X is 62.4 g/mol? b. What is the atomic mass of element X if 9.94 g XCl3 contains 3.26 g X? c. A 2.953-g sample of an oxide of V contains 1.654 g V. What is the empirical formula of the oxide? d. What is the empirical formula of a hydrocarbon if complete combustion or 6.900 mg of the hydrocarbon...
What compound provides the explosive force in aerial fireworks?
What compound provides the explosive force in aerial fireworks?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT