In: Chemistry
The most appropriate response for a reaction that is spontaneous at all temperatures would be
(a) ΔHº = - ΔSº = +
(b) ΔHº = + ΔSº = -
(c) ΔHº = - ΔSº = -
(d) ΔHº = + ΔSº = +
Answer: (a)
A reaction will be spontaneous when it has a negetive free energy value. The change in free energy will have always negetive value when the reaction is exothermic (change in enthalpy, = negetive) with more disorder (change in entropy, = positive). This can be explained with the help of following equation.
The change in spontaneous nature of reaction with change in enthalpy and entropy is given below,