Question

In: Chemistry

3.) Consider this reaction data. A⟶products T (K) k (s–1) 275 0.383 875 0.659 If you...

3.) Consider this reaction data.

A⟶products

T (K) k (s–1)
275 0.383
875 0.659

If you were going to graphically determine the activation energy of this reaction, what points would you plot? To avoid rounding errors, use at least three significant figures in all values.What is the activation energy of this reaction? Determine the rise, run, and slope of the line formed by these points.

point 1: ?=

point 1: ?=

Solutions

Expert Solution

We need to plot lnK on y axis and 1/T on x axis

K = 0.383

ln K = ln (0.383) = -0.95972

T = 275.0

1/T = 0.00364

point 1 is:

x = 0.00364

y = -0.95972

K = 0.659

ln K = ln (0.659) = -0.41703

T = 875.0

1/T = 0.00114

point 2 is:

x = 0.00114

y = -0.41703

----------------------------------------------------------------------------

rise = (y1-y2) = -0.95972 - -0.41703 = -0.54269

rise = (X1-X2) = 0.00364 - 0.00114 = 0.00249

slope = rise/run

= -0.54269/0.00249

= -217.64072

----------------------------------------------------------------------------

use

slope = - Ea/R

= -217.64072 = -Ea/8.314

Ea = 1809 J/mol


Related Solutions

Consider the reaction A → products at 312 K. For this reaction it was observed that...
Consider the reaction A → products at 312 K. For this reaction it was observed that the first three half-lives were 11.3 h, 22.6 h, and 45.2 h when [A]o 1.343 M. How long will it take for [A] to decrease by 63 %? Time for [A] to decrease by 63 % (in hours)= second order
Consider the reaction A → products at 312 K. For this reaction it was observed that...
Consider the reaction A → products at 312 K. For this reaction it was observed that the first three half-lives were 11.3 h, 22.6 h, and 45.2 h when [A]o 1.343 M. How long will it take for [A] to decrease by 63 %? Time for [A] to decrease by 63 % (in hours)= I believe second order
Consider the reaction A -> products at 312 K. For this reaction it was observed that...
Consider the reaction A -> products at 312 K. For this reaction it was observed that the first three half lives were 10.7 h, 5.35 h, and 2.675 h when [A] 2.873M. How long will it take for [A] to decrease by 47%? Time for [A] to decrease by 47% (in hours) = Anwser is 10.1h need help on how to get this anwser.
Let K = { s+t * 2^(1/2), such that s, t are Rational}. Show that K...
Let K = { s+t * 2^(1/2), such that s, t are Rational}. Show that K is a Field
Consider the reaction A → products at 311 K. The concentration of A was monitored over...
Consider the reaction A → products at 311 K. The concentration of A was monitored over time and the data was analyzed by plotting. It was found that a plot of 1/[A] vs time gave a straight line relationship. It was also observed that it took 24.5 s for the concentration of A to decrease from 0.757 M to 0.107 M. What is the half life for this reaction when [A]o = 0.757 M?
Consider the reaction A → products at 282 K. The concentration of A was monitored over...
Consider the reaction A → products at 282 K. The concentration of A was monitored over time and the data was analyzed by plotting. It was found that a plot of ln[A] vs time gave a straight line relationship. It was also observed that it took 20.7 s for the concentration of A to decrease from 0.689 M to 0.235 M. What is the half life for this reaction when [A]o = 0.689 M? t1/2 (in seconds)
Consider the table of data collected for the reaction A → Products.
Consider the table of data collected for the reaction A → Products. Determine the magnitude (value) of the reaction rate constant by graphing the data appropriately. 
For a given reaction, the rate constant is k'= 2.0 * 10^-4 L*mol^-1*s^-1 at T' =...
For a given reaction, the rate constant is k'= 2.0 * 10^-4 L*mol^-1*s^-1 at T' = 298K and k= 4.5 * 10^-3 L*mol^-1*s^-1 at T=345K Calculate the Arrhenius parameter A
The rate constant for a certain reaction is k = 1.90×10−3 s−1 . If the initial...
The rate constant for a certain reaction is k = 1.90×10−3 s−1 . If the initial reactant concentration was 0.850 M, what will the concentration be after 15.0 minutes? A zero-order reaction has a constant rate of 2.80×10−4 M/s. If after 75.0 seconds the concentration has dropped to 9.00×10−2 M, what was the initial concentration? A zero-order reaction has a constant rate of 2.80×10−4M/s. If after 75.0 seconds the concentration has dropped to 9.00×10−2M, what was the initial concentration?
For the reaction A + H2O → products, find the rate of the reaction when [A] = 0.75 M, k= 0.02. a) 0.077 s-1 b) 0.085 s-1 c) 0.015 s-1 d) 0.026 s-1
For the reaction A + H2O → products, find the rate of the reaction when [A] = 0.75 M, k= 0.02. a) 0.077 s-1 b) 0.085 s-1 c) 0.015 s-1 d) 0.026 s-1
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT