In: Chemistry
What is the term used for reactions or processes that are spontaneous and have a negative Gibbs Free Energy?
Gibb,s Free energy of spontanaeous processes :
According to first law of thermodynamics the total energy of isolated system always remains constant. Gibb,s free energy is atate function & is extensive property given by the following equation:
Delta G = Delta H -T Delta S
for spontanaeous processe delta S is alway positive i.e. Delta S >0.
T Delta S- Delta H > 0
Delta H -T Delta S < 0
Therefore , Delta G < 0
Hence, for the spontanaeous processes Gibb,s free energy change is negative when the temperature is high. All spontanaeous processes are irreversibble.