Question

In: Chemistry

Calculate the enthalpy of reaction for the following reaction using Hess's Law and the equations provided...

Calculate the enthalpy of reaction for the following reaction using Hess's Law and the equations provided below.

Target Reaction: Sr(s)+C(graphite)+1 1/2 O2(g) -----> SrCO3(s) H(degrees)=?

C(Graphite)+ O2(g)-----> CO2(g) H(degrees)= -349kJ

Sr(s)+ 1/2 O2(G)-------> SrO(s) H(degrees)= -592kJ

SrO(s)+CO2(g)-------> SrCo3(s) H(degrees)= -234kJ

Solutions

Expert Solution

first of all, you have witten the target equation wrongly it should be

Sr (s) + (3/2) O2 (g) + C (graphite) ---> SrCO 3 (s)

(A) Sr (s) + (1/2) O2 (g) ---> SrO (s) dH = -592 kJ
(B) SrO (s) + CO2 (g) ---> SrCO 3 (s) dH = -234 kJ
(C) C (graphite) + O2 (g) ---> CO 2 (g) dH = -394 kJ

we use 1 equation (B) to provide the product , SrCO 3 (s)
we use 1 equation (A) to provide the Sr as a starting material
we use 1 equation (C) to provide the C as a starting material
(we are not concerned with providing the necessary O2, since it is provided from more than 1 source

combining 1 (A) & 1(B) & 1 (C) gives:
Sr + (1/2) O2 & SrO (s) + CO2 (g) & C (graphite) + O2 (g) ---> SrO (s) & SrCO 3 (s) & CO 2
we notice that
SrO (s) --> cancels out .--> SrO (s)
CO2 (g) --> cancels out .--> CO2 (g)

leavng only your desired equation
Sr (s) + (3/2) O2 (g) + C (graphite)--> SrCO 3 (s)


Hess's law says that if adding 1 (A) & 1(B) & 1 (C) gives you the equation you wish,
the combining the dH's from 1 (A) & 1(B) & 1 (C) gives you the dH you wish

-592 kJ & -234 kJ & -394 kJ = -1220 kJ
your answer is
dH = -1220 kJ


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