Question

In: Chemistry

Ideal gas with Cp=32 State 1 (P=1bar T=300 k) compressed isothermally volume becomes 1/2 (state 2),...

Ideal gas with Cp=32

State 1 (P=1bar T=300 k) compressed isothermally volume becomes 1/2 (state 2),

State 3 gas is compressed adiabatic to P3=4 bar,

State 4 ideal gas is expanded isothermally to unknown P4.

Finally gas is compresses back to stage 1.

Fill the blanks in the table for both T and P in all states showing your work

Pressure P (bar) Temperature T (K)
State 1 1 300
State 2
State 3 4
State 4

Solutions

Expert Solution

Given:

For 1 mole of gas

Step 1

Isothermal Compression

Hence, temeperature remains constant.

from

hence,

For an ideal gas, PV = constant for an isothermal process.

Hence,

Step 2

Adiabatic Compression.

Increasing pressure to 4 bar without heat or mass transfer to the system.

Also, for an ideal gas

hence,

Now,

here we have used ideal gas equation for 1 moles of gas PV = RT , Hence, V = RT/P.

Since R is a constant we can tak eit to the side of constant.

Using the values of .

Now,

Step 3

Isothermal expansion

Since this process is isothermal,

Again, using the relation

We cannot determine the unknown P4 as we do not know to what volume the isothermal expansion has been done. As heat is added to maintain the temperature at a constant volume, as long as the heat is being added, the system will keep expanding and the value of PV is going to be constant throughout.

Pressure (bar) temeprature (K)
State 1 1 300
State 2 2 300
State 3 4 359
State 4 ? 359

Related Solutions

A perfect gas occupying a volume of 200 dm3 at 2 atm is isothermally compressed at...
A perfect gas occupying a volume of 200 dm3 at 2 atm is isothermally compressed at 500K with a piston actuated at external pressure, Pext, constant. Q3a) What will be the smallest value of Pext for a final volume of 50 dm3? Q3b) Calculate the work, w, done with this value of Pext. Is this a reversible or irreversible work? Q3c) This same gas is then compressed isothermally and reversibly at 500K V1 = 200 dm3 at V2 = 50...
5 moles of ideal gas is initially at 300 K and 5 bar. It is compressed...
5 moles of ideal gas is initially at 300 K and 5 bar. It is compressed to 10 bar at 300 K. This change is carried out by two different reversible processes: A: heating at constant volume followed by cooling at constant pressure B: cooling at constant pressure followed by heating at constant volume Depict these processes on a PT graph. (Hand drawn on engineering sheet would suffice). Calculate ΔU, ΔH, Q, and W requirements for each path. Cv=20.78 J/mol.K...
One kg mole of an ideal gas is compressed isothermally at 127°C from 1 atm to...
One kg mole of an ideal gas is compressed isothermally at 127°C from 1 atm to 10 atm in a piston-and-cylinder arrangement. Calculate the entropy change of the gas, the entropy change of the surroundings, and the total energy change resulting from the process, if: (a) the process is mechanically reversible and the surroundings consist of a heat reservoir at 127°C. (b) the process is mechanically reversible and the surroundings consist of a heat reservoir at 27°C. (c) the process...
One mole of an ideal gas (CP = 5R/2) in a closed piston/cylinder is compressed from...
One mole of an ideal gas (CP = 5R/2) in a closed piston/cylinder is compressed from Ti = 298 K, Pi = 0.1 MPa to Pf = 0.25 MPa by the following pathways. For each pathway, calculate ΔU, ΔH, Q, and WEC: (a) isothermal; (b) constant volume; (c) adiabatic. i need your help as soon as possible please!!! please give me step by step so i can understand it Thank you!
Three moles of an ideal gas expand isothermally and reversibly from 90 to 300 L at...
Three moles of an ideal gas expand isothermally and reversibly from 90 to 300 L at 300 K. a) Calculate ΔUm, ΔSm, w per mole, and q per mole. b) If the expansion is carried out irreversibly by allowing the gas to expand rapidly into a vacuum, determine ΔUm, ΔSm, w per mole, and q per mole
One mole of an ideal gas (CP/R=7/2), is compressed in a steady-flow compressor from 2.5 bar...
One mole of an ideal gas (CP/R=7/2), is compressed in a steady-flow compressor from 2.5 bar and 25°C to 6.5 bar and 120°C. The compressor rejects 0.5 kJ as heat to the surrounding at 293K. Calculate: 1.     The enthalpy change of the gas (in kJ) 2.     The entropy change of the gas (in J.mol-1) 3.     The work required for the compression (in kJ) 4.     The ideal work of the process (in kJ) 5.     The thermodynamic efficiency The lost work (in kJ)
A 1 mole, 293 K gas expands isothermally, starting at 22.4 L in volume. What is...
A 1 mole, 293 K gas expands isothermally, starting at 22.4 L in volume. What is its final volume? Only solve with variables, not numarically.
An ideal gas with Cp = 2.5R at 298 K and 5.00 bar is adiabatically throttled...
An ideal gas with Cp = 2.5R at 298 K and 5.00 bar is adiabatically throttled to 1.00 bar. If the flow rate of gas is 1.71 mol/s, and the surroundings are at a temperature of 3°C, what is the rate of lost work, in kW? Please give your answer to 3 SF, and be very careful with units.
2. A 1.00L piston with 1.00mole of an ideal gas at 298.0K and 1.00bar is isothermally...
2. A 1.00L piston with 1.00mole of an ideal gas at 298.0K and 1.00bar is isothermally and reversibly compressed to a final volume of 0.100L, then irreversibly expanded in 1 step to its original volume with an applied pressure of 1.00bar. a. (6 pts) Calculate the change in heat for the system (q sys) for the compression and expansion steps. b. (6 pts) Calculate the change in entropy for the compression and expansion steps. Show step by step and i...
2) An ideal gas cycle operates via the following 4 stages: 1→2 The gas is compressed...
2) An ideal gas cycle operates via the following 4 stages: 1→2 The gas is compressed adiabatically 2→3 The gas is ignited and heated at constant pressure 3→4 The gas expands adiabatically 4→1 Heat is removed from the gas at constant pressure a) Draw the cycle on a pressure-volume diagram, labelling the states 1, 2, 3, and 4 and showing where heat enters the cycle and where heat is removed from the cycle. Identify the highest pressure phigh and lowest...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT