Question

In: Chemistry

The Kb of dimethylamine [(CH3)2NH] is 5.90×10-4 at 25°C. Calculate the pH of a 1.80×10-3 M...

The Kb of dimethylamine [(CH3)2NH] is 5.90×10-4 at 25°C. Calculate the pH of a 1.80×10-3 M solution of dimethylamine.

Solutions

Expert Solution

The ionization of dimethyl amine is

(CH3)2NH + H2O <=> (CH3)2NH2+ + OH-

Kb= [CH3)2NH2+] [OH-]/ [(CH3)2NH]

ICE table is prepared

compound                        initial                                 change                  equilibrium

(CH3)2NH                    1.8*10-3                                  -x                           1.8*10-3-x

(CH3)NH2+                        0                                        x                             x

OH-                                    0                                        x                             x

Kb= x2/(1.8*10-3-x)= 5.9*10-4 , when solved using excel, x= 7.78*10-4, [OH-]= 7.78*10-4, pOH= 3.1, pH= 14-3.1=10.9


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