1. At SATP, which reaction below is spontaneous?
2NaF(s)+Cl2(g)→2NaCl(s)+F2(g)
2KCl(s)+I2(g)→2KI(s)+Cl2(g)
2F(g)→F2(g)
O2(g)→2O(g)
2. For which of these is there an increase in entropy?
H2O(l)+CO2(g)→H2CO3(aq)
2Na3PO4(aq)+3CaCl2(aq)→6NaCl(aq)+Ca3(PO4)2(s)
Ba(OH)2(s)+2NH4Cl(s)→BaCl2(aq)+2NH3(g)+2H2O(l)
H2O(g)→H2O(s)
3.
Calculate ∆Sº for the reaction below:
N2(g)+2O2(g)⇄2NO2(g)
where ∆Sº for N2(g), O2(g), &
NO2(g), respectively, is 191.5, 205.0, & 240.5
J/mol-K
-156.0 J/K
156.0 J/K
120.5 J/K
-120.5 J/K
4. ∆Svap for H2O at its boiling point and
1 atm is (∆Hvap of H2O = 40.7kJ/mol)
109 J/K
40,700 J/K
407 J/K...