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Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory to standardize strong...


Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory to standardize strong base solutions. It has the unwieldy formula of KHC8H4O4. This is often written in shorthand notation as KHP.
What volume of a 0.201 M sodium hydroxide solution is needed to exactly neutralize 1.55grams of KHP ?
ANSWER: ____ mL sodium hydroxide

Potassium hydrogen phthalate is a solid, monoprotic acid frequently used in the laboratory to standardize strong base solutions. It has the unwieldy formula of KHC8H4O4. This is often written in shorthand notation as KHP.
If 0.481 grams of KHP are needed to exactly neutralize 23.1 mL of a sodium hydroxide solution, what is the concentration of the base solution?
ANSWER: ____ M sodium hydroxide

Solutions

Expert Solution

The reaction between KHC8H4O4 (KHP)and NaOH goes like this

Hence 1 mol NaOH neutralises 1 mol of KHP.

Part 1

Amount of KHP to be neutralised = 1.55 g

Molar mass of KHP = 204.22 g/mol

Hence, number of moles of KHP to be neutralised is

Concentration of base NaOH being used = 0.201 M = 0.201 mol/L

Number of moles of NaOH needed to neutralise KHP = .

Hence, volume of 0.201 M that contains the required number of moles is

Hence, answer is 37.8 mL of NaOH.

Part 2

Volume of NaOH that is being neutralised = 23.1 mL

Amount of KHP being used = 0.481 g

Number of moles of KHP being used =

Hence, number of moles of NaOH present in 23.1 mL must be .

Hence, the concetration of NaOH solution is

Hence, the answer is 0.102 M NaOH.


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