Question

In: Chemistry

Can someone show me how to calculate theoretical yield using glacial acetic acid as an example?

Can someone show me how to calculate theoretical yield using glacial acetic acid as an example?

Solutions

Expert Solution

Solution:

The yield calculation that you perform for most synthetic procedures is based on the comparision of moles of product isolated and moles of product that you can theoretically obtain based on the the limiting reagent.

Let's look at one simple example. Suppose, a student reacts 30.0 g acetic acid and 100 mL of ethanol in the presence of 2 mL of concentrated sulfuric acid and he obtains 42 g of the crude ester and 39.5 g after purification (distillation).

Step 1: Write balanced equation ( in presence of H2SO4)

CH3COOH + CH3CH2OH = CH3COOCH2CH3

MW 60g 46g 88g

Step 2:Identify limitiing reagent- For this calculate the no of moles of each reagent, and in this case we find the minimum no of moles of H2SO4 and hence it is limiting reagent.

Step 3: Calculation of yield

Firstly, How many moles of the product did he isolate?

This is calculated by weight divided by MW.

Crude: 42 g/(88 g/mol)= 0.47 mol

Purified: 39.5 g/(88 g/mol)=0.45 mol

b. Yields:

Calculate the moles of CH3COOH= weight/ MW = 30g / 60g = 0.50 mol

Then, Yield = [actual number of moles ( moles of ester )/theoretical number of moles (moles of acetic acid)x100%]

Crude yeild = (0.47 mol/0.50 mol) x100% = 94%

Purified yeild = (0.45 mol/0.50 mol) x 100% = 90 %


Related Solutions

Calculate the theoretical yield if 46g of salicylic acid is reacted with 27 g of acetic...
Calculate the theoretical yield if 46g of salicylic acid is reacted with 27 g of acetic anhydride.
How to find theoretical yield using 6 mL 1-propanol, 10 mL acetic acid and 1 mL...
How to find theoretical yield using 6 mL 1-propanol, 10 mL acetic acid and 1 mL sulfuric acid.
Calculate the theortical yield and percent yield using 2.027g of salicylic acid, 4.5 mL of acetic...
Calculate the theortical yield and percent yield using 2.027g of salicylic acid, 4.5 mL of acetic anhydride, and 5 drops of conc. H2SO4. The actual yield of the product is 2.357g. i need help asap.
Can someone show me how to write a Haskell function using snd on a list of...
Can someone show me how to write a Haskell function using snd on a list of tuples to create a new list of just the second element in each tuple? Ex. [(‘m’, False), (‘w’, False), (‘n’, True)] would evaluate to [False, False, True].
How to calculate the theoretical yield of luminol? Starting with 200 mg of 3- nitrophthalic acid
How to calculate the theoretical yield of luminol? Starting with 200 mg of 3- nitrophthalic acid
Write the ionization reaction of aniline, C6H5NH2, in glacial acetic acid, and identify the conjugate acid...
Write the ionization reaction of aniline, C6H5NH2, in glacial acetic acid, and identify the conjugate acid of aniline. Write the ionization reaction of phenol, C6H5OH, in ethylene diamine, NH2CH2CH2NH2, and identify the conjugate base of phenol.
How many mL of glacial acetic acid is needed to prepare 1 mole of butyl acetate...
How many mL of glacial acetic acid is needed to prepare 1 mole of butyl acetate if reaction occurs in 100% yield. MM acetic acid=60.05, density=1.05g/mL
Starting with 7.2 g of salicylic acid, how many grams of acetylsalicylic acid (theoretical yield) can...
Starting with 7.2 g of salicylic acid, how many grams of acetylsalicylic acid (theoretical yield) can be made? Assume salicylic acid is the limiting reagent and a one to one stoichiometry. Use the molecular weights that you have already calculated. Give two significant digits.
Calculate the theoretical yield for the bromination of bothstilbenes and cinnamic acid, assuming the presence of...
Calculate the theoretical yield for the bromination of bothstilbenes and cinnamic acid, assuming the presence of excesspyridinium tribromide. cinnamic acid - 150 mg cis-stilbene - 100 μL trans- stilbene - 100 mg pyridinium tribromide - 200-385 mg
Calculate the theoretical yield for the bromination of bothstilbenes and cinnamic acid, assuming the presence of...
Calculate the theoretical yield for the bromination of bothstilbenes and cinnamic acid, assuming the presence of excesspyridinium tribromide. cinnamic acid - 150 mg cis-stilbene - 100 μL trans- stilbene - 100 mg pyridinium tribromide - 200 mg
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT