Question

In: Chemistry

1. Which molecule or ion has the same molecular geometry as SeO32–? A.SO3 B.NO3– C.CO32– D.SO32–...

1.

Which molecule or ion has the same molecular geometry as SeO32–?

A.SO3

B.NO3

C.CO32–

D.SO32–

E.SeO3

2.

Which of the following processes is not exothermic?

A. Rb+(g)+e- = Rb(g)

B. Br(g)+e- = Br-(g)

C. Rb+(g)+Br-(g) = RbBr(s)

D. Rb(g) = Rb(s)

E. 1/2 Br2 (g) = Br(g)

Solutions

Expert Solution

1 ) answer : D.SO32–

explanation:

(i) SeO32– is pyramidal molecule hybridisation sp3. .SO32–   here also S participate in sp3 hybridisation molecule shape is pyramidal

(ii) SO3 . in this moelcule S participate in sp2 hybridisation. molecule shape is planar

(iii) NO3- . N hybridisation sp2 . shape planar

(iv) CO3-2 . C hybridisation sp2 . shape planar

(v) SeO3 . se hybridisation sp2 . shape planar

2) answer: E). 1/2 Br2 (g) --------------> Br(g)

explanation :

A. Rb+(g)+e- --------------> Rb(g) --------------> electron affinity (exothermic)

B. Br(g)+e- ----> Br-(g) --------------> electron affinity (exothermic)

C. Rb+(g)+Br-(g) ----> RbBr(s)---------------> lattice energy (exothermic)

D. Rb(g) -----------> Rb(s) ----------------> compression of gas to solid (exothermic)

E. 1/2 Br2 (g) ---> Br(g)--------------> de-atomisation needs energy (endothermic)


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