In: Chemistry
Until roughly 1970, tritium (3H), a radioactive isotope of hydrogen, was a component of fluorescent watch dials and hands. For 3H, t1/2 = 12.3 yr. Assume you have such a watch. If a minimum of 12.0% of the original tritium is needed to read the dial in dark places, for how many years could you read the time at night? Assume first-order kinetics.
Given,
t1/2 of the tritium(3H) = 12.3 years
Assuming,
the initial amount of tritium in the watch (No) = 100 %
The amount of tritium remaining after time "t" (Nt) = 12.0 %
Firstly calculating the decay constant() from the given half-life period of 3H,
= 0.693 / t1/2
= 0.693 /12.3 yr
= 0.05634 yr-1
We know, the first order equation,
ln [Nt / No] = - x t
Substituting the known values,
ln [12 / 100] = - 0.05634 yr-1 x t
t = 37.6 years