Question

In: Chemistry

Until roughly 1970, tritium (3H), a radioactive isotope of hydrogen, was a component of fluorescent watch...

Until roughly 1970, tritium (3H), a radioactive isotope of hydrogen, was a component of fluorescent watch dials and hands. For 3H, t1/2 = 12.3 yr. Assume you have such a watch. If a minimum of 12.0% of the original tritium is needed to read the dial in dark places, for how many years could you read the time at night? Assume first-order kinetics.

Solutions

Expert Solution

Given,

t1/2 of the tritium(3H) = 12.3 years

Assuming,

the initial amount of tritium in the watch (No) = 100 %

The amount of tritium remaining after time "t" (Nt) = 12.0 %

Firstly calculating the decay constant() from the given half-life period of 3H,

= 0.693 / t1/2

= 0.693 /12.3 yr

= 0.05634 yr-1

We know, the first order equation,

ln [Nt / No] = - x t

Substituting the known values,

ln [12 / 100] = - 0.05634 yr-1 x t

t = 37.6 years


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