Question

In: Chemistry

1. Write the overall balanced equation corresponding to this abbreviated cell notation: Cr / Cr3+ //...

1. Write the overall balanced equation corresponding to this abbreviated cell notation: Cr / Cr3+ // Pb4+ , Pb2+ / Pt (Explain Reasoning)

2. Write the abbreviated cell notation for the reaction: 2Al(s) + 3 Cd(NO3)2 => 3 Cd + 2 Al(NO3)3 (Explain Reasoning)

Solutions

Expert Solution

(1)        Cr / Cr3+ // Pb4+ , Pb2+ / Pt

      anodic RXN     cathodic RXN

At anode oxidation takes place & at cathode reduction reaction takes place.

Anode : Cr Cr3+ + 3e-

Cathode : Pb4+ +2e- Pb2+

Overall cell reaction is : Pb4+ +Cr Pb2+ +Cr3+

         0           +2                   0        +3

(2) 2Al(s) + 3 Cd(NO3)2 3 Cd + 2 Al(NO3)3

The two half reactions are (1) Al Al3+   ( oxidation at anode)

                                       (2) Cd3+ Cd ( reduction at cathode)

The cell notation reaction :    anodic reaction // cathode reaction

                                       Al / Al3+ // Cd3+ / Cd


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