Question

In: Chemistry

A pure gas contains 81.71% carbon and 18.29% hydrogen by mass. Its density is 1.97 g/L

A pure gas contains 81.71% carbon and 18.29% hydrogen by mass. Its density is 1.97 g/L

Solutions

Expert Solution

element             %                 A.Wt             relative number          simple ration               simplest ratio

C                    81.71                12                   81.71/12   = 6.8         6.8/6.8 = 1                    1*3 = 3

H                    18.29                 1                    18.29/1 = 18.29        18.29/6.8   = 2.68         2.68*3 = 8

The empirical formula = C3H8

The empirical formula mass = 12*3 + 8 = 44g/mol

molecular formula = ( empirical formula)n

   At STP

molar mass = volume * density

                     = 22.4L/mole* 1.97g/L    = 44g/mole

n   = molar mass/empirical formula mass

      = 44/44 = 1

molecular formula = (C3H8)1 = C3H8


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