Question

In: Chemistry

3. a. What effect does temperature have on the reaction rate of oxalic acid and permanganate?...

3. a. What effect does temperature have on the reaction rate of oxalic acid and permanganate? b. Will temperature have an effect on the equilibrium constant of this reaction?

Solutions

Expert Solution

3H2C2O4 + 2KMnO4 6CO2 + 2KOH + 2H2O + 2MnO2

Rate = k[KMnO4][H2C2O4]

Here, temperature increase increases the rate of a chemical reaction. By increasing the temperature not only increases the number of collisions but also increases the energy of the collisions and get a greater probability that some of those collisions have sufficient energy to overcome this barrier. There is another factor that comes into play called the orientation factor, though it is not very important in this reaction. This factor takes into account the number of collisions that occur at the correct location to effect breakage of the desired bond.

Changes in temperature will change the equilibrium constant.


Related Solutions

Experiment: Studying the Rate of the Reaction of Potassium Permanganate and Oxalic Acid BRIEFLY EXPLAIN THE...
Experiment: Studying the Rate of the Reaction of Potassium Permanganate and Oxalic Acid BRIEFLY EXPLAIN THE MEANING OF THE FOLLOWING TERMS AS THEY PERTAIN TO THIS EXPERIMENT. A. REACTION RATE B. RATE EQUATION C. RATE CONSTANT D. OVERALL REACTION ORDER
1. what effect does a catalyst have on the reaction rate? explain 2. predict how the...
1. what effect does a catalyst have on the reaction rate? explain 2. predict how the reaction rate would change if the concebtration of the sodium meta-bisulfite soltion were changed insted of the potassium iodate concentration.
In the reaction of copper with potassium permanganate and sulfuric acid, the products are copper (II)...
In the reaction of copper with potassium permanganate and sulfuric acid, the products are copper (II) sulfate, potassium sulfate, water, and manganese (II) sulfate. First, write a balanced net ionic equation for this reaction. Then consider the reaction taking place with 100 grams of copper, 100 grams of potassium permanganate, and 400 grams of sulfuric acid. How many grams of manganese (II) sulfate could be produced in this reaction?
14-Consider the following reaction at equilibrium. What effect will increasing the temperature have on the system?...
14-Consider the following reaction at equilibrium. What effect will increasing the temperature have on the system? Why?             CO2(g) + 2 H2O(l) ⇌ CH4(g) + 2 O2(g)      ΔH° = +890 kJ 15-Consider the following reaction at equilibrium. What effect will decreasing the temperature have on the system? Why?             C3H8(g) + 5 O2(g) ⇌ 3 CO2(g) + 4 H2O(l)   ΔH° = -2220 kJ Coal, which is primarily carbon, can be converted to natural gas, primarily CH4, by the exothermic reaction:...
Explain why temperature has an effect on reaction rate. Explain why concentration has an effect on...
Explain why temperature has an effect on reaction rate. Explain why concentration has an effect on reaction rate.
What kind of an effect does an enzyme have on the rate of the forward and...
What kind of an effect does an enzyme have on the rate of the forward and reverse reactions, the energy of the products and reactants and the energy of the transition state?
What effect will methanol have on the rate of reaction of sodium phenoxide with ethyl iodide?...
What effect will methanol have on the rate of reaction of sodium phenoxide with ethyl iodide? is this a good solvent for this type of mechanism? why do you think this solvent is used
Factors affecting reaction rates 1) In the presence of a strong acid, permanganate ion reacts with...
Factors affecting reaction rates 1) In the presence of a strong acid, permanganate ion reacts with oxalic acid according to the following net ionic equation: 2MnO?4(aq)+5H2C2O4(aq)+6H+(aq)?10CO2(g)+2Mn+2(aq)+8H2O(l). Which of the following permanganate solutions will have the fastest reaction rate? Answers a. 4.01 g of KMnO4 dissolved in 2L of 1.0N H2SO4 b. 2.10 g of KMnO4 dissolved in 500mL of 1.0N H2SO4 c. 7.25 g of KMnO4 dissolved in 2000mL of 1.0N H2SO4 d. 4.21 g of KMnO4 dissolved in 0.750L...
Experiment IV: Effect of pH on the Rate of Enzyme Reaction 3. What could be done...
Experiment IV: Effect of pH on the Rate of Enzyme Reaction 3. What could be done to more specifically determine the optimal pH?
What effect does all three of the following variables have on yeast fermentation? a) temperature b)...
What effect does all three of the following variables have on yeast fermentation? a) temperature b) food scarcity c) pH Please explain all three, thanks, have on yeas
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT