Chemistry 2 Lab question!
How is sulfate ion seperated from NO3 - and Cl - ?
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What is precipitation hardening? Is this a kinetics or thermodynamic process? Explain.
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Part A
The activation energy of a certain reaction is 39.4kJ/mol . At 30 ?C , the rate constant is 0.0190s?1. At what temperature in degrees Celsius would this reaction go twice as fast?
Express your answer with the appropriate units.
Part B
Given that the initial rate constant is 0.0190s?1 at an initial temperature of 30 ?C , what would the rate constant be at a temperature of 150 ?C for the same reaction described in Part A?
Express your answer with the appropriate units.
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A "silver" ring was purchased at a local store. It was stamped "sterling silver" which means that it must contain 92.5% by mass Ag. The remaining 7.5% may technically be any other metal. Copper is typically used for this. This ring was found to be magnetic, which suggests that the non silver part may contain iron or nickel as well. A small amount of the ring is dissolved in nitric acid, making a solution of the nitrate of any metal that would be present.
a. What group does each of the four metals belong to?
b. After the removal of the silver as the insoluble chloride, the solution is made basic with 6M NH4OH. If the solution turns Violet, with no blue color present, what cation was present in the solution?
c. What would the cation present be if the solution turned a very strong navy blue color instead, when the amonium hydroxide was added?
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how many moles and numbers of ions each type,are present Iin the following aqueous solution? 51.5 ml of 1.55 M magnesium chlorides
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how many grams of NaOH must be added to 1L of a 0.1 M
KH2PO4 to prepare a pH 7.42 buffer. answer given by professor is
2.47 I need help understanding how to solve
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a.
1. | 0.29 m | NiSO4 | A. | Lowest freezing point | ||
2. | 0.18 m | BaI2 | B. | Second lowest freezing point | ||
3. | 0.16 m | CuCl2 | C. | Third lowest freezing point | ||
4. | 0.51 m | Sucrose(nonelectrolyte) | D. | Highest freezing point |
b. Match the following aqueous solutions with the
appropriate letter from the column on the right.
1. | 0.16 m | Ca(NO3)2 | A. | Lowest freezing point | ||
2. | 0.18 m | Ca(NO3)2 | B. | Second lowest freezing point | ||
3. | 0.25 m | KOH | C. | Third lowest freezing point | ||
4. | 0.44 m | Ethylene glycol(nonelectrolyte) | D. | Highest freezing point |
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whic of these interactions can be explained by hydrogen bonding.
Select all that apply.
HF is a weak acid neutralized by NaOH. | |
HF has a higher boiling point than HCl. | |
CH4 molecules interact more closely in the liquid than in the gas phase. | |
Ice, H2O, has a solid structure with alternating H?O interactions. | |
H2Te has a higher boiling point than H2S. |
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a. An aqueous solution is made by dissolving
18.4 grams of iron(III) bromide
in 314 grams of water.
The molality of iron(III) bromide in the solution
is ________m.
b.In the laboratory you are asked to make a
0.473 m chromium(II) acetate
solution using 425 grams of
water.
How many grams of chromium(II) acetate should you
add?
_________ grams.
c. The boiling point of diethyl ether
CH3CH2OCH2CH3
is 34.50°C at 1 atmosphere. A nonvolatile,
nonelectrolyte that dissolves in diethyl ether is
chlorophyll.
If 10.38 grams of chlorophyll,
C55H72MgN4O5
(893.5 g/mol), are dissolved in
236.2 grams of diethyl
ether.
The molality of the solution is ______ m.
The boiling point of the solution is______ °C.
d. The freezing point of benzene
C6H6 is
5.50°C at 1 atmosphere. A nonvolatile,
nonelectrolyte that dissolves in benzene is
DDT .
If 14.38 grams of DDT,
C14H9Cl5
(354.5 g/mol), are dissolved in
276.5 grams of benzene ...
The molality of the solution is _____ m.
The freezing point of the solution is _________°C.
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Consider the titration of 35.0 mL of 0.260 M HF with 0.215 MNaOH. Calculate the pH at each of the following points.
Part A.)
How many milliliters of base are required to reach the equivalence point?
Express your answer using three significant figures.
Part B.)
Calculate the pH after the addition of 8.75 mL of base
Express your answer using two decimal places.
Part C.)
Calculate the pH at halfway to the equivalence point.
Express your answer using two decimal places.
Part D.)
Calculate the pH at the equivalence point.
Express your answer using two decimal places.
Part E.)
Calculate the pH after the addition of 70.0 mL of base.
Express your answer using two decimal places.
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1. Where do the typical IR absorption come for the following functional groups.
Alcohol
Alkyl
Alkene
Alkyne
Aromatics
Carboxylic acids
2.
Where do the typical IR absorption comes for amines?
Primary amines
Secondary amines
Tertiary amines
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The chief compound in marble is CaCO3. Marble has been widely used for statues and ornamental work on buildings, including such structures as the Taj Mahal (Figure 1) . However, marble is readily attacked by acids via the following reaction. CaCO3(s)+H+(aq)⇌Ca2+(aq)+HCO3−(aq) Equilibrium constants at 25 ∘C are listed in the table below.
CaCO3 Ksp =4.5×10−9
H2CO3 Ka1 =4.3×10−7
H2CO3 Ka2 =5.6×10−11
Part A What is the molar solubility of marble (i.e., [Ca2+] in a saturated solution) in normal rainwater, for which pH=5.60?
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A well mixed 10m3 closed mixing tank at 18C is used to dilute 100kg/min of a 2.0% by mass NaClO3 solution to a 0.60% solution by adding water.
Part 1) What is the mass flowrate of water into the tank needed at steady-state to accomplish this dilution?
Part 2) You notice that some gas bubbles appear in the effluent, and after some additional literature reading, hypothesize that NaCl3 is decomposing to NaCl and O2 inside the tank because of impurities in its walls. You do not have an oxygen detector handy and so decide to build a 0.5m3 chamber above the tank to collect all the gas generated. Initially the pressure (absolute) in this collection chamber is 760mmHg. After five minutes you measure the pressure to be 1320mmHg.
a) if your hypothesis is correct, what is the mass rate of oxygen generation?
b) assuming that the NaCl3 solution flowing in and the NaCl3/NaCl solution flowing out each have a density of 1.0g/mL (which will be within 1% of truth), what is the concentration (g/L) of NaCl in the effluent?
c) if a portion of water from the effluent were evaporated without any additional decomposition occuring, what would be the purity of the NaClO3?
d) after more literature reading, you believe that the rate of NaClO3 decomposition is directly proportional to the molar concentration of NaClO3 in the tank and the tank volume, Based on this hypothesis, determine the value of the proportionality constant, thereby obtaining a general expression for the rate of NaClO3 decomposition.
Part 3) The dilution water has been flowing and the NaClO3 decomposing at steady state rate. suddenly, the valve controlling the flow of dilution water malfunctions and closes, halting its flow. assuming the densities of all the solutions are approximately the same, how much time passes before the concentration of NaClO3 in the effluent exceeds 1%?
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Please answer as soon as possible (Chemical Engineering)
Given The reactions
C3H8 → C3H6 + H2
C3H8 + 2H2 → 3CH4
The feed contains 90.0 mole% propane(C3H8) and the balance inert. The fractional conversion of propane is 0.603 and the fractional yield of propylene is 0.541.
Calculate the molar composition of the product gases and selectivity of ethylene to methane production.
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Explain why the addition of a small amount of base to an acidic buffer solution causes only a small change in the pH of the buffer solution. You should use any appropriate chemical and/or mathematical equations to substantiate your arguments
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