Questions
​ Given the following reaction and thermodynamic data, what is a reccomended temperature for a 1...

Given the following reaction and thermodynamic data, what is a reccomended temperature for a 1 L pilot scale reactor and how long (time) does it take for the reaction to take place?

CH3OCH2CH2CH2OCH2NH2 -> CH3OCH2CH2CH2OH + CH2=NH

Species

CH3OCH2CH2CH2OCH2NH2

CH3OCH2CH2CH2OH

CH2NH

Hf (Kcal/mol)

-91.15

-92.23

19.75

S (cal/mol/K)

118.08

97.18

54.18

300

39.13

29.37

8.92

400

48.84

36.69

10.39

500

56.65

42.77

11.99

600

63.34

48.03

13.47

800

74.69

56.74

15.95

1000

82.87

62.98

17.87

1500

0

0

21.02

ΔHrxn (Kcal/mol)

ΔSrxn (cal/mol/K)

ΔGrxn (Kcal/mol)

Kp

18.67

33.28

8.69E+03

0.985534268

18.494

32.77367955

5.38E+03

0.993248201

18.292

32.31453957

2.13E+03

0.99785361

18.118

32.00460919

-1.08E+03

1.0009103

17.67

31.31834149

-7.38E+03

1.004656425

17.256

30.84797494

-1.36E+04

1.0068639

43.894

67.11038492

-5.68E+04

1.019230233

Kc

A-forward (sec^-1)

Ea(Kcal/mol)

K-forward (sec^-1)

0.001653304

2.10611E+14

53.09

4.40801E-25

0.001249683

2.80815E+14

52.914

3.42895E-15

0.001004382

3.51018E+14

52.712

3.18437E-09

0.000839549

4.21222E+14

52.538

3.06178E-05

0.000632018

5.61629E+14

52.09

3.295681283

0.000506726

7.02037E+14

51.676

3561.584427

0.000341966

1.05305E+15

78.314

4084.744896

Delta S+c (cal/mol/K)

A-backward (sec^-1)

K-backward (sec^-1)

-24.11856204

45429261.35

9.50818E-32

-23.54895154

59940560.67

7.31917E-22

-23.10712731

74049093.99

6.7176E-16

-22.74613063

87957142.2

6.39344E-12

-22.17652012

114260467

6.70489E-07

-21.73469589

139369642.5

0.000707053

-20.93187498

531011737.2

0.002059767

In: Chemistry

Ions B and C to form the complex BC. If 35.0 mL of 1.00 M B...

Ions B and C to form the complex BC. If 35.0 mL of 1.00 M B is combined with 35.0 mL of 1.00 M C, 0.00500 mol of BC is formed. Determine the equilibrium constant fo this reaction.

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Considering the reaction 2Al2O3+3C ----> 4Al +3CO2 A- How many moles of C are needed to...

Considering the reaction 2Al2O3+3C ----> 4Al +3CO2

A- How many moles of C are needed to react with 7.75 moles of Al2O3?

B- How many grams of Al result when 355 grams of Al2O3 react?

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6. You mix 50.0 mL of a weak monoprotic acid with 50.0 mL of NaOH solution...

6. You mix 50.0 mL of a weak monoprotic acid with 50.0 mL of NaOH solution in a coffee cup calorimeter. Both solutions (and the calorimeter) were initially at 22.0OC. The final temperature of the neutralization reaction was determined to be 22.5OC. a) What is the total amount of heat evolved in this reaction? Show all work. b) If 0.135 moles of the monoprotic acid were neutralized in this reaction, what is the molar heat of neutralization (enthalpy) for this reaction?

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calculate the equilibrium concentration of H2CO3 and HCO3 in 1.0M Na2CO3 at 25 Celsius

calculate the equilibrium concentration of H2CO3 and HCO3 in 1.0M Na2CO3 at 25 Celsius

In: Chemistry

Part1. Calculate the nuclear binding energy (in J) and the nuclear binding energy per nucleon of...

Part1. Calculate the nuclear binding energy (in J) and the nuclear binding energy per nucleon of

241 Pu
94

(241.0568453 amu).

Part 2.

A freshly isolated sample of 90Y was found to have an activity of 8.2 × 105 disintegrations per minute at 1:00 p.m. on December 3, 2006. At 2:15 p.m. on December 17, 2006, its activity was measured again and found to be 2.2 × 104 disintegrations per minute. Calculate the half-life of 90Y.



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Given 855cm^3 of a 0.00330M silver nitrate is mixed with 424cm^3 of a .0110M potassium chromate...

Given 855cm^3 of a 0.00330M silver nitrate is mixed with 424cm^3 of a .0110M potassium chromate find,

a) balanced equation for both substances when placed in water

b) equation for the net ionic reaction

c) Ksp expression

d) concentration of all ions in solution after mixing but before any reaction takes place

In: Chemistry

QUESTION 1 We will be using spectrophotometry to determine the concentration of iron in solutions. First,...


QUESTION 1

We will be using spectrophotometry to determine the concentration of iron in solutions. First, you will generate a calibration curve. The ----- variable is -----, and will be graphed on the x axis of the calibration curve. The -------- variable is ----------, and will be graphed on the --------- axis.

Word Bank:

-independent

-y

-absorbance

-dependent

-concentration

QUESTION 2

How many mL of a 100 mg/dL Ferrozine solution are needed to complex 0.00000048 moles of iron?

HINT: Look at the 1st equation in the lab manual (under the heading Background)

PUT YOUR ANSWER IN DECIMALS (not scientific notation)

QUESTION 3

How many moles of Fe3+ can be reduced by 1.1 mL of 0.527 M hydroxylamine solution?

Look at the 2nd equation in your lab manual under the heading Background to see the relationship between Iron and hydroxylamine.

Put your answers in DECIMALS, not scientific notation.

QUESTION 4

The trendline equation calculated from a calibration curve of absorbance vs iron concentration in μg dL-1 is y = 0.000812x + 0.00709. If a sample analyzed using the same assay gives an absorbance of 0.099, what is the iron concentration of the unknown sample in μg dL-1?

This is a simple "equation of a line" formula.

QUESTION 5

As part of this laboratory, you may have to remove iron from a solution. If you have 50 mL of a solution that contains 239 μg dL-1, how many μg of iron must be removed to reach a concentration of 150 μg dL-1?

HINT: 1. Convert 50mL to dl;

2. Figure out how much μg of solution you have in that 50 mL

3. Figure out how much μg of solution you want in 50 mL

4. Subtract the answers from 2 & 3.

QUESTION 6

As part of this laboratory, you may have to add iron to a solution. If you have 100 mL of a solution that contains 45 μg dL-1, how many grams of iron must be added to reach a concentration of 150 μg dL-1?

Put your answer in scientific notation

QUESTION 7

The concentration of the iron stock solution for this lab is 500 μg dL-1. What volume of this solution (in mL) must you add to the "patient" sample to give your patient 0.00000003 moles of iron?


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1.    Write A for anti- addition or S for syn-addition to alkenes on the line provided...

1.    Write A for anti- addition or S for syn-addition to alkenes on the line provided for each of the following:

_______ Hydroxylation with cold Permanganate oxidation

---------------Catalytic hydrogenation

-------------Bromination

-----------------Chlorination

_______ Halohydrin formation

       ___ Hydroxylation with Osmium tetroxide

_______ Hydroboration/oxidation (Non-Markovnikov addn)

_______ Hydroxylation by acid -catalyzed epoxide hydrolysis

_______ Epoxidation with a peroxyacid

________Carbenes addition to yield cyclopropanes

_________ Ozonolysis in forming the molozonide

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Briefly state the principle of a Faraday Cup detector for a mass spectrometer.

Briefly state the principle of a Faraday Cup detector for a mass spectrometer.

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How does a Fourier Transform Infrared Spectrometer (FTIR) work? Summarize the method and give figures and...

How does a Fourier Transform Infrared Spectrometer (FTIR) work? Summarize the method and give figures and curves to explain the description.
Give at least 3 references.

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For each of the following sets of chemicals, predict their relative reactivity in the given type...

For each of the following sets of chemicals, predict their relative reactivity in the given type of reaction mechanism. List them in order (from least reactive to most reactive) and explain why (the one most significant cause for this trend of reactivity).

a) 1-chlorobutane vs 1-chloro-2-butene in SN1

b) 2-chlorobutane vs 1-chloro-2-butene in SN1

c) 1-chlorobutane vs 1-chloro-2-methylpropane in SN2

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The following reversible gas-phase reaction is carried out in a 10 L batch reactor. A <->C...

The following reversible gas-phase reaction is carried out in a 10 L batch reactor.
A <->C -rA = CA – 0.5CC [mol/(L h)]
Determine the pressure, temperature, and gas phase composition (mole fractions) in the reactor after 1
hour of operating adiabatically given the following initial conditions and physical properties and the
assumption of ideal gas behavior:
P0 = 100 kPa, yA0 = 0.5, yC0 = 0.1, yinert=0.4, T0 = 500 K.
cpA = cpC = 10 J/mol K, cpinert = 5 J/mol K, HR(298K) = -20 kJ/mol C formed

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What is the vapor pressure of a solution of 300 g of ethylene glycol, HOCH2CH2OH (mol...

What is the vapor pressure of a solution of 300 g of ethylene glycol, HOCH2CH2OH (mol wt = 62.1) and 200 g of water (a 60% solution by weight) at 100 ºC. The vapor pressure of pure water is 760 torr at 100 ºC (the boiling point of water).

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1)A typical commercial antacid tablet contains 0.350 g of CaCO3 [MW=100.09 g/mol] as an active ingredient....

1)A typical commercial antacid tablet contains 0.350 g of CaCO3 [MW=100.09 g/mol] as an active ingredient. How many moles of HCl could this tablet neutralize? 2)A student was analyzing an antacid tablet with a mass of 2.745 g. The student found that a 1.872 g sample of the tablet would neutralize 67.35 mL of stomach acid. Calculate how much stomach acid would be neutralized by the entire tablet. 3)A student determined that 29.43 mL of 0.132 M NaOH reacts with 25.0 mL of stomach acid. He dissolved a commercial tablet of antacid into 180 ml of stomach acid and then removed a 20.0 mL of the resulting solution. The Titration of this 20 mL sample took 9.56 mL of NaOH. Calculate volume of acid neutralized by antacid in the 200mL sample. 4) A 0.248 g sample of antacid containing an unknown amount of triprotic base Al(OH)3 [MW=78.00 g/mol] was reacted with 25.0 mL of 0.121 M HCl. The resulting solution was then titrated with 12.26 mL of 0.132M NaOH solution. Calculate the mass percent of Al(OH)3 in the antacid sample

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