Is the six-membered ring system in benzene particularly stable or unstable? Explain using chemical concepts
In: Chemistry
How will I find the pI for a non-ionizable amino acid?
In: Chemistry
The Separation of Three Organic Compounds by Acid, Base Reactions and Liquid, Liquid Extraction.
Okay, so we had solid benzoic acid, ethyl 4- aminobenzoate, and 9-fluorenone all dissolved in diethyl ether. We separated the basic component by adding 3M HCl, we separated the acidic component by adding 3M NaOH. I don't understand what happens here. To isolate the acidic solution, we added 6 M NaOH and used the vacuum to recover the solid. To isolate the basic solution we added 6M HCl. I did an experiment where a 1:1:1 mixture of Benzoic Acid solid (C6H5COOH), ethyl 4-aminobenzoate solid (C9H11NO2), and 9-fluorenone solid (C13H8O) was dissolved with methylene chloride. Then each component was extracted and tested. I need to come up with a proton transfer chemical reaction that represents what happened in each separation. First separation: HCl was added and two layers formed. aqueous layer was extracted and transfer to a clean container and methylene chlotide layer was left aside. NaOH was added dropwise to aqueouse layer extraction and vacuum filtration was used to extract/separate the basic component ethyl 4-aminobenzoate solid (C9H11NO2).
Results &Data:
1)Benzoic acid (Acid)
|
Benzoic acid |
0.051g |
|
Tare dish |
0.419 g |
|
Dish with Solid (Benzoic acid) |
0.443 g |
|
Dry mass obtained (Final product after vacumming) |
0.441 g |
|
Melting point |
97.0 °C – 97.2 °C |
Table 1: Collected data from Benzoic acid
2) Benzoate (Base)
|
Benzoate |
0.050 g |
|
Tare dish |
0.406 g |
|
Dish with Solid (Benzoate) |
0.413 g |
|
Dry mass obtained (Final product after vacumming) |
0.408 g |
|
Melting point |
78.0 °C – 79.4 °C |
Table 2: Collected data from Benzoate.
3) 9-Fluorenone (Neutral)
|
9-Fluorenone |
0.050 g |
|
Tare tube |
11.360 g |
|
Dry mass obtained (Final product after drying) |
11.470 g |
|
Melting point |
89.4 °C – 89.5 °C |
Table 3: Collected data from 9-Fluorenone.
I need to find the theoretical and percent yield of each product, how many mg of each product is present. And also create 4 chemical reactions. Need help, Please help thankyou
In: Chemistry
Calculate the change in standard-state entropy for the following reaction that results in the formation of glucose:
6 CO2(g) +6 H2O(l) ⟶ 1 C6H12O6(s) + 6 O2(g)
(If applicable, coefficients of one have been included for clarity.)
Express your answer with the appropriate units. Use FOUR significant figures.
In: Chemistry
|
# |
[Myoglobin] (mg/mL) |
Myoglobin stock volume (mL) |
[GuHCl] (M) |
GuHCl stock volume (mL) |
Phosphate buffer volume (mL) |
Total volume (mL) |
|
1 |
0.2 |
0 |
1000 |
|||
|
2 |
0.2 |
0.4 |
1000 |
|||
|
3 |
0.2 |
0.8 |
1000 |
|||
|
4 |
0.2 |
1.0 |
1000 |
|||
|
5 |
0.2 |
1.2 |
1000 |
|||
|
6 |
0.2 |
1.3 |
1000 |
|||
|
7 |
0.2 |
1.4 |
1000 |
|||
|
8 |
0.2 |
1.5 |
1000 |
|||
|
9 |
0.2 |
1.6 |
1000 |
|||
|
10 |
0.2 |
1.7 |
1000 |
|||
|
11 |
0.2 |
1.8 |
1000 |
|||
|
12 |
0.2 |
2.0 |
1000 |
|||
|
13 |
0.2 |
2.2 |
1000 |
|||
|
14 |
0.2 |
2.6 |
1000 |
|||
|
15 |
0.2 |
3.0 |
1000 |
In: Chemistry
Describe the procedure you would follow to determine the concentration of Vitamin C in a sample if the volume of DCPIP required to reach the endpoint was more than the 25-mL flask could hold. Note the titration must still be carried out in the flask. Be sure to include any calculations you would need to perform.
In: Chemistry
Calculate Delta H rxn for the following reaction (watch the
significant figures)
2 NOCl (g) --> N2(g) + 02(g) + Cl2(g)
Given the following set of reactions;
1/2 N2(g) + 1/2 02(g) ---> NO(g) Delta H= 90.3KJ
NO(g) + 1/2 Cl2(g) ---> NOCl(g) Delta H = - 38.6 KJ
In: Chemistry
Chromic acid (H2CrO4) is an acid that is used in ceramic glazes and colored glass. The pH of a 0.070 M solution of chromic acid is the same as the pH of a 0.054 M HNO3 solution. Calculate Ka for chromic acid.
In: Chemistry
A hydrogen-oxygen fuel cell is used in the space program to generate clean energy. Describe, in detail, the principle and process of electrical energy generation from hydrogen-oxygen fuel cell. Also include in the discussion major advantages and limitations of such fuel cells.
In: Chemistry
The solutions at the two Pb electrodes of a concentration cell were prepared as follows:
Cell A: A mixture of 1.00 mL of 0.0500 M Pb(NO3)2 with 4.00 mL of 0.0500 M KX (the soluble potassium salt of an unspecified monovalent ion X-). Some PbX2(s) precipitates.
Cell B: 5.00 mL of 0.0500 M Pb(NO3)2.
The cell potential was measured to be 0.05100 V at 25 °C.
1.)By use of the Nernst equation, determine the concentration (M) of Pb2+ in the solution of Cell A.
2.)In Cell A, how many moles of X- have reacted with Pb2+?
3.)What is the concentration (M) of X- in the solution of cell A.
4.) Calculate Ksp of PbX2.
In: Chemistry
(a) Calculate the standard free-energy change (ΔG°) for the following oxidation-reduction reaction. Cu(s) + Br2(aq) → Cu2+(aq) + 2 Br−(aq)
(b) Calculate the equilibrium constant for this reaction at 298 K.
In: Chemistry
Describe the preparation of 40 L 0.02 M phosphate buffer, pH 6.9 starting from Solid KH2PO4 and K2HPO4
In: Chemistry
What is the minimum mass of ice at 0.0 C that must be added to 1 kg of water to cool the water from 28 C to 12 C? (heat of fusion = 333 J/g, Specific heat capacity of ice = 2.06 J/g K, water = 4.184J/g K)
In: Chemistry
Determine whether the entropy increases or decreases in the given situations.
a. A vapor that turned to solid
b. A vapor condenses to a liquid
c. A mole of vapor becomes solid
d. A liquid freezes
e. A solute dissolved in a solvent
In: Chemistry
A rigid stainless steel chamber contains 210 Torr of methane, CH4, and excess oxygen, O2, at 200.0
In: Chemistry