Hess's Law:
Calculate ΔH for the neutralization
of HCl(aq) by
NaOH(s). I'M NOT
SURE WHAT DATA YOU NEED, SO I COPY AND PASTED ALL OF MY
DATA.
A. ΔHsolution of NaOH(s) Phase
Change:
Mass of NaOH: 2.05 g
ΔT for reaction A : 8.0 °C
B. ΔHsolution for neutralization of
HCl(aq) and NaOH(aq):
Volume of HCl: 0.0500 L
Volume of NaOH: 0.0500 L
Volume total: 0.100 L
Molarity of HCl: 1.95 M
Molarity of NaOH: 1.95 M
ΔT for reaction B: 11.0°C
C. ΔH for Reaction of HCl(aq) and
NaOH(s):
Volume of HCl: 0.0550 L
Volume of water: 0.0450 L
Volume total: 0.100 L
Molarity of HCl: 1.95 M
Mass of NaOH: 3.44 g
ΔT for reaction C: 17°C
D. ΔH for Solution of KCl(s) in
water:
ΔT for reaction D: -5.0°C
Mass of KCl: 5.02 g
Volume of water: 0.0500 L
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In the following reaction what mass of Ba(NO3)2 can be formed by combining 55.0g BaCO3 and 55.0g HNO3? BaCO3+2HNO3=Ba(NO3)2+CO2 +H2O
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A. Calculate the pH using the quadratic and the approximate approaches.
Approximate method yields pH = 2.47
Quadratic methods yields pH = 2.49
B Calculate the percent error introduced in the hydrogen ion concentration if the approximate solution was chosen
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1 a. A buffer solution is prepared by placing 5.86 grams of sodium nitrite and 32.6 mL of a 4.90 M nitrous acid solution into a 500.0 mL volumetric flask and diluting to the calibration mark. If 12.47 mL of a 1.43 M solution of potassium hydroxide is added to the buffer, what is the final pH? The Ka for nitrous acid = 4.6 X 10-4.
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Classify each of the following reactions as one of these four types:
• spontaneous at all temperatures
• not spontaneous at any temperature
• spontaneous below a certain temperature but not above
• spontaneous above a certain temperature but not below See Table 17.1 in Tro, Fridgen and Shaw.
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