Question

In: Chemistry

12.      Predict the direction of the equilibrium shift when temperature is decreased in the following reactions:...

12.      Predict the direction of the equilibrium shift when temperature is decreased in the following reactions:

a.         C2H2 (g) + H2O (g) ? CH3CHO (g)      [?H = -151 kJ/mol]

b.         CH3CH2OH (l) + O2 (g) ? CH3CH2O (g) + H2O (g)      [?H = exothermic]

c.         2 CH3CHO (g) ? 2 C2H4 (g) + O2 (g)      [?H = endothermic]

13.            Consider the following endothermic reaction for the production of hydrogen gas in a rigid container:

CH4(g) + H2O(g) ? CO(g) + 3 H2(g)

How will the yield of hydrogen change if the equilibrium is disturbed by:

a.         Adding a catalyst.

b.         Increasing the pressure.

c.         Decreasing the temperature.

d.         Adding inert argon gas.

e.         Increasing the temperature.

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