Question

In: Chemistry

Which of the following pairs of atomic orbitals on adjacent nuclei can overlap to form a...

Which of the following pairs of atomic orbitals on adjacent nuclei can overlap to form a sigma bond? A pi bond? Which cannot overlap (no bond)? Consider the x-axis to be the internuclear axis.
a) 1s and 2s
b) 3py and 2py
c) 2px and 3pz.

Solutions

Expert Solution

Sigma bond : a) 1s and 2s

Pi bond : b) 3py and 2py

No bond : c) 2px and 2pz

s orbital is sperical shape and two s orbial form sigma bond along the nuclear axis

p arbitals are directional and form pi bonds if two direction of two p orbital matching.


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