Analyze the ? bonding in the nitrite anion (NO2?) using a molecular orbital scheme. Use the...

Analyze the ? bonding in the nitrite anion (NO2?) using a molecular orbital scheme. Use the approach we used in lecture to work on the trans-1,3-butadiene molecule.

(a) Determine the ? MOs that are obtained by constructive overlap of the 2p orbitals. Arrange them

from low energy to high energy in terms of their bonding and antibonding character.

(b) Make an energy level diagram for the ? MOs and populate it with the ? electrons.

(c) From the energy level diagram, determine the effective bond order for each of the bonds. What does this information imply about the structure of the molecule?

(d) Determine the electron configuration for the first excited state, and determine then how the

structure changes when light is absorbed owing to an optical transition from the ground state to

the first excited state. Note that the way you combine the 2p orbitals in part (a) must respect the

symmetry of the molecule. For example, if there is a ? node in one of your MOs, it must not move if you interchange the O

atoms by rotating the molecule. (This means that one of your MOs must have a node that goes through one of the atoms....

Expert Solution

queen_honey_blossom answered 2 years ago

Molecular Orbital Theory -- Homodiatomics Use the molecular orbital model to fully describe the bonding in...

Molecular Orbital Theory -- Homodiatomics Use the molecular orbital model to fully describe the bonding in O2+, O2, O2-, and O22-. Determine which of the following statements are true and which are false. The electron configuration of O2- is (σ2s)2(σ2s*)2(σ2p)2(π2p)4(π2p*) The electron configuration of O2+ is (σ2s)2(σ2s*)2(σ2p)2(π2p)4(π2p*) The number of unpaired electrons in O2+ and O22- is, respectively, 1 and 2. The bond lengths increase in the order: O2+ < O2 < O2- < O22-. The bond order in O2+...

Use Molecular Orbital theory to show why cyclobutadiene is antiaromatic but the cyclopentadienyl anion is aromatic....

Use Molecular Orbital theory to show why cyclobutadiene is antiaromatic but the cyclopentadienyl anion is aromatic. (Hint: use the polygon rule to predict the molecular orbital energy diagrams).

what does it mean that a molecular orbital is antibonding or bonding?

What is the diference between an atomic orbital and a molecular orbital? WHich bonding theories are...

What is the diference between an atomic orbital and a molecular orbital? WHich bonding theories are each type of orbital applicable/relevant?

let us consider the case of a bonding electron in a diatomic molecule using molecular orbital...

let us consider the case of a bonding electron in a diatomic molecule using molecular orbital theory. Given that the probabilities of finding the electron in atomic orbitals ?A and ?B are 1/3 and 2/3, respectively, what is the LCAO-MO wavefunction for the electron? (Neglect the overlap integral as a simplifying approximation)

Use Molecular Orbital Theory to describe bonding in the following. Also find the bond order and...

Use Molecular Orbital Theory to describe bonding in the following. Also find the bond order and decide if stable or not. Is species dia or paramagnetic? i. C2+ ii. Be2+ iii. Ne2

Why antibonding 2s molecular orbital is filled before a bonding 2p molecular orbital, although antibonding 2s...

Why antibonding 2s molecular orbital is filled before a bonding 2p molecular orbital, although antibonding 2s molecular orbital reduces stability?

Draw a schematic representations (orbital overlap) of each bonding and antibonding molecular orbital in BH-4

Would a molecular orbital diagram be appropriate to describe bonding in Ti? Explain.

Which of the following best describes the molecular orbital theory of bonding? Choose one: A. A...

Which of the following best describes the molecular orbital theory of bonding? Choose one: A. A theory where the bonds and lone pairs of valence electrons in a molecule are represented in two-dimensions B. A theory of bonding based on the mixing of atomic orbitals of similar shapes and energies to form molecular orbitals that extend to two or more atoms C. A theory that predicts the arrangement of valence electron pairs around a central atom minimizing their mutual repulsion...

Question