Question

In: Chemistry

What type of bond (sigma or pi) will result from the overlap of the following orbitals...

What type of bond (sigma or pi) will result from the overlap of the following orbitals on adjacent atoms? a) H(s)-C(sp3) b) C(sp2)-C(sp3) c) C(sp3)-N(p) d) C(p)-O(p)

Solutions

Expert Solution

(a) H(s)-C(sp3) ---> Sigma Bond

s-orbital has spherical symmetrical structure. So, s-orbital containing atom (H) always form "sigma bond".

(b) C(sp2)-C(sp3) ---> Sigma Bond

sp3 hybridized carbon always form "sigma bond".

(c) C(sp3)-N(p) ---> Sigma Bond

sp3 hybridized carbon always form "sigma bond".

(d) C(p)-O(p) ---> Pi Bond

We know that pi-bond between two adjacent atoms formed by lateral overlap of two p-orbitals.

As C and O both contain p-orbitals. Hence, pi bond will form.


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