Question

In: Chemistry

Q1: If the theoretical yield of a reaction is 24.8 g and the actual yield is...

Q1: If the theoretical yield of a reaction is 24.8 g and the actual yield is 18.5 g, what is percent yield?

Q2: When 11.5 gram of C are allowed to react with 114.5 g Cu2O, 87.4 g of Cu are obtained. Determine the limiting reactant, theoretical yield and percent yield.

Q3:This reaction of 185 g of Fe2O3 with 95.3 g of CO produces 87.4 g of Fe. Determine limiting reactant, theoretical yield, and percent yield.

Solutions

Expert Solution

Q1: If the theoretical yield of a reaction is 24.8 g and the actual yield is 18.5 g, what is percent yield?

Percent yield = (actual yield/theoretical yield) * 100.

Percent yield = (18.5/24.8)*100 = 74.596%

Percent yield = 74.596%

Q2: When 11.5 gram of C are allowed to react with 114.5 g Cu2O, 87.4 g of Cu are obtained. Determine the limiting reactant, theoretical yield and percent yield.

                   2Cu2O + C ----> 4Cu + CO2

First convert 11.5 gram of C, 114.5 g Cu2O and 87.4 g of Cu into moles

Moles of C = Wt/M.Wt = 11.5/12.01 = 0.957 moles

Moles of Cu2O = Wt/M.Wt = 114.5/143.09 = 0.80 moles

Moles of Cu = Wt/M.Wt = 87.4/63.546 = 1.375 moles

                   2Cu2O + C ----> 4Cu + CO2

From equation 2 moles of Cu2O reacts with one mole of C and generates 4 moles of Cu.

So for 2 moles of Cu2O, one mole of C is required.

So for given 0.80 moles of Cu2O, 0.40 moles of C is required. So 0.557 (0.957-0.40 = 0.557) moles of C will remain in the reaction. So limiting reagent in this reaction is Cu2O.

Theoretical yield:

2 moles of Cu2O reacts and generates 4 moles of Cu.

Then 0.80 moles Cu2O generates 1.60 moles of Cu.

Convert 1.60 moles of Cu in to grams

Theretical yield (Weight)= moles x M.Wt = 1.60 x 63.546 = 101.67 gm

Theretical yield = 101.67 gm

Percent yield

Percent yield = (actual yield/theoretical yield) * 100.

Percent yield = (87.4/101.67)*100 = 85.96 %

Percent yield = 85.96%

Q3:This reaction of 185 g of Fe2O3 with 95.3 g of CO produces 87.4 g of Fe. Determine limiting reactant, theoretical yield, and percent yield.

Fe2O3 + 3CO ==è 2Fe + 3CO2

First convert 185 g of Fe2O3, 95.3 g of CO and 87.4 g of Fe into moles

Moles of Fe2O3 = Wt/M.Wt = 185/159.69 = 1.158 moles

Moles of CO = Wt/M.Wt = 95.3/28.01 = 3.40 moles

Moles of Fe = Wt/M.Wt = 87.4/55.845 = 1.565 moles

Fe2O3 + 3CO ==è 2Fe + 3CO2

From equation one mole of Fe2O3 reacts with three moles of CO and generates 2 moles of Fe.

So for Three moles of CO, one mole of Fe2O3 is required.

So for given 3.40 moles of CO, 1.133 moles of Fe2O3 is required. So 0.024 (1.158-1.133 = 0.024) moles of Fe2O3 will remain in the reaction. So limiting reagent in this reaction is CO.

Theoretical yield:

one mole of Fe2O3 reacts and generates 2 moles of Fe.

Then 1.158 moles Fe2O3 generates 2.316 moles of Fe.

Convert 2.316 moles of Fe in to grams

Theretical yield (Weight)= moles x M.Wt = 2.316 x 55.845 = 129.33 gm

Theretical yield = 129.33 gm

Percent yield

Percent yield = (actual yield/theoretical yield) * 100.

Percent yield = (87.4/129.33)*100 = 67.579 %

Percent yield = 67.579%


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