Question

In: Chemistry

Determine the pH of each of the following solutions. A) 2.00×10−2 M HClO4 B) 0.120 M...

Determine the pH of each of the following solutions.

A) 2.00×10−2 M HClO4

B) 0.120 M HClO2

C) 3.5×10−2 M Sr(OH)2

D) 8.60×10−2 M KCN

E) 0.150 M NH4Cl

Solutions

Expert Solution


A) pH of strong acid (HClO4): pH = -log[H+] = -log(2.00*10^-2) = 1.699

B) pH of weak acid(HClO2): pH = 1/2(pKb-log(C)) =
                          
                              = 1/2(1.96-log(0.120)) = 1.44

c) pOH of Sr(OH)2(strong base): pOH = -log(OH-) = -log(2*1.35*10^-2) = 1.569

   pH of the solution =14 -pOH = 14-1.569 = 12.431

D) pH salt of strong base and weak acid (KCN) = 7+ 1/2(pKa +log(c))

                                              = 7+1/2(-log(Ka)+log(C))

                                               = 7+1/2(-log(4.0*10^-10)+log(8.60*10^-2)

                                               = 11.166

E) pH salt of WEAK base and STRONG acid (NH4Cl) = 7- 1/2(pKb +log(c))

                                              = 7-1/2(-log(Kb)+log(C))

                                               = 7-1/2(-log(1.8*10^-5)+log(0.150))

                                               = 5.03


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