An unknown compound (A), C10H12O, gave the following proton NMR
data: (a) triplet, at 1.0 ppm...
An unknown compound (A), C10H12O, gave the following proton NMR
data: (a) triplet, at 1.0 ppm (3H) (b) quartet, at 2.4 ppm (2H) (c)
singlet, at 3.7 ppm (2H) (d) multiplet, at 7.2 ppm (5H) Propose a
structure for (A).
1. if a compound has a NMR resonance at 9.5 ppm , and
an IR absorbance at 2550cm^-1, what functional group does the
molecule contain?
a) ketone
b)alkyne
c)carboxylic acid
d)aldehyde
e)amine
f) nitrile
2. when examining an NMR spectra you see peaks between
7-8 ppm. Which of the following compounds would assume you were
analyzing?
a) benzene
b) (e) 3-penten-2-one
c)2-cyclopropene-1-carboxylic acid
d) formylcyclohexane
Identify the compound A (C5H10O) with the proton NMR spectrum
shown. Compound A has IR absorptions at 3200–3600 cm–1 (strong,
broad), 1676 cm–1 (weak), and 965 cm–1, and also has 13C NMR
absorptions (attached protons in parentheses) at δ 17.5 (3), δ 23.3
(3), δ 68.8 (1), δ 125.5 (1), and δ 135.5 (1). Compound A may be
resolved into enantiomers; draw one molecule of A, omitting
wedge/dash bonds.
The proton NMR spectrum for a compound with the formula C7H14O
is shown below along with carbon-13 spectral data in tabular form.
(It may be necessary to expand (zoom) some of the 1H signals to
view spin-spin splitting details.)
This compound exhibits strong infrared absorption at
1717 cm-1, but the 1500-1650 cm-1 region is
empty.
13C Data
Normal Carbon
DEPT-135
DEPT-90
Proton Shift
Relative Area
13.8
Positive
No peak
0.91
3.2
17.2
Negative
No peak
1.09
5.8
18.2
Positive
No...
Combustion of 8.732 mg of an unknown organic compound gave
16.432 mg of CO2 and 2.840 mg of H2O. (a) find the wt% of C and H
in the substance. (b) Find the smallest reasonable integer mole
ration of C:H in the compound.
Deduce the identity of the following compound from the spectral
data given.
C9H10O2: 13C NMR, δ
18.06 (quartet), 45.40 (doublet), 127.32 (doublet), 127.55
(doublet), 128.61 (doublet), 139.70 (singlet), 180.98 (singlet);
IR, broad 3500-2800, 1708 cm-1
Part A Table of C-13 NMR data for
1-phenylcyclohexanol using the following headings
for each compound (carbon types: CH, CH2, CH3, CH-OH, etc) Chemical
Shift (ppm) Carbon Type
Part B Table of C-13 NMR data for
1-phenylcyclohexene using the following headings
for each compound (carbon types: CH, CH2, CH3, CH-OH, etc):
Chemical Shift (ppm) Carbon Type
Give detailed explanation of the chemical Shift only and show
the carbon labeled.
elemental analysis of an unknown compound was found to give the
following data 70.4% carbon, 8.08% hydrogen and 10.12 % of
nitrogen. it was found to have a molecular weight of 137.18 Da.
determine the empirical formula, molecular formula, and the degree
of unsaturation for this compound
The following data were obtained from experiments to find the
molecular formula of an unknown compound which acts as a common
local anesthetic. The unknown compound contains only carbon,
hydrogen, nitrogen, and oxygen. Complete combustion of a 4.82 g
sample of the unknown compound with excess oxygen formed 12.67 g of
carbon dioxide and 4.076 g of water. Another sample of the unknown
compound with a mass of 1.12 g was found to contain 0.1339 g of
nitrogen. The molar...
Independent random samples from two regions in the same area
gave the following chemical measurements (ppm). Assume the
population distributions of the chemical are mound-shaped and
symmetric for these two regions. Region I: , 1008 852 567 749 764
727 945 657 880 773 1023 1002 Region II: , 1070 750 879 836 711
1070 706 866 608 892 891 965 998 1089 852 443 Let be the population
mean for and be the population mean for Find a 90%...