Question

In: Chemistry

1. If by mistake, chemist used 100% ethanol rather than THF as a solvent, would the...

1. If by mistake, chemist used 100% ethanol rather than THF as a solvent, would the synthesis proceed as expected? Why or why not?

2. Why is bromotoluene added dropwise to the reaction flask rather than all at once?

3. Draw a dipole moment (see chapter 1) to explain the polarity of the following Grignard reagent?

MgBr

1. In this reaction we will be heating butadiene sulfone to perform a Diels-Alder reaction. What side product is generated upon heating butadiene sulfone and how will we trap this side product?

2. In most chemical reactions it is a bad idea to create a closed system, that is a system which cannot attenuate to pressure changes. In this reaction what measures are taken to avoid a closed system and why would it be a particularly bad idea to create a closed system for this Diels-Alder reaction?

Solutions

Expert Solution

1. If by mistake, chemist used 100% ethanol rather than THF as a solvent, would the synthesis proceed as expected? Why or why not?

Solution :- In the Grignard reagent experiment the Grignard reagent RMgX is having alkyl group with negative charge that is R^-. This acts as base so it can easily take up the H from the alcohol to form the alkane product so the reaction does not occur as expected. Polar protic solvent is not used in the Grignard reactions so we cannot use the 100% ethanol since it is protic solvent which is not helpful in the Grignard reaction.

2. Why is bromotoluene added dropwise to the reaction flask rather than all at once?

Solution :- Addition of the bromotolune dropwise helps to form the Grignard salt. If the bromotolune is added all time then it may lead to vigorous reaction so to avoid that bromotolune is added dropwise.

1. In this reaction we will be heating butadiene sulfone to perform a Diels-Alder reaction. What side product is generated upon heating butadiene sulfone and how will we trap this side product?

Solution :- The side product formed in the reaction is the SO2 gas which is generated from the butadiene sulfone on heating. Therefore we can trace this by the observing the bubbling in the reaction mixture.

2. In most chemical reactions it is a bad idea to create a closed system, that is a system which cannot attenuate to pressure changes. In this reaction what measures are taken to avoid a closed system and why would it be a particularly bad idea to create a closed system for this Diels-Alder reaction?

Solution :- If the system is closed then gases formed during the reaction would not escape from the system which causes the pressure build up in the system which can cause the explosion of the apparatus. So it is bad idea to use the closed system in the Diels Alder reaction.


Related Solutions

Why would you use methanol rather than ethanol as a recrystalizing solvent for methyl m-nitrobenzoate? (not...
Why would you use methanol rather than ethanol as a recrystalizing solvent for methyl m-nitrobenzoate? (not because of boiling point)
The common laboratory solvent ethanol is often used to purify substances dissolved in it. The vapor...
The common laboratory solvent ethanol is often used to purify substances dissolved in it. The vapor pressure of ethanol, CH3CH2OH, is 54.68 mm Hg at 25 °C. In a laboratory experiment, students synthesized a new compound and found that when 30.10 grams of the compound was dissolved in 269.1 grams of ethanol, the vapor pressure of the solution was 53.72 mm Hg. The compound was also found to be nonvolatile and a non-electrolyte. What is the molecular weight of this...
Why would you prefer to receive $100 today rather than wait and receive $100 one year...
Why would you prefer to receive $100 today rather than wait and receive $100 one year from now? Prompts: For the first part of the discussion post, list all the potential explanations you can think of for the time value of money. For each cause, write a sentence or two about how it explains your preference for money today rather than money at some future date. Let’s see how many different explanations we can uncover. For the second part of...
1.What is the function of ethanol in this aldol condensation? A.Ethanol is the solvent for the...
1.What is the function of ethanol in this aldol condensation? A.Ethanol is the solvent for the reaction. B.None of the answers shown are correct. C.Ethanol is used to remove a proton from the carbonyl group of 3,4-dimethoxybenzaldehyde. D.Ethanol is the recrystallization solvent. 2.Assume the two reactants were in equimolar amounts to begin with but you used 2.0 g of 1-indanone in the reaction instead of 0.20 g, how might this affect your final yield? A.Yield would be doubled. B.YIELD WOULD...
why is it important to know that most people would rather have $90 today than $100...
why is it important to know that most people would rather have $90 today than $100 next year and why?
Ethanol (C2H5OH) is a very important chemical.in addition to being widely used as an industrial solvent,a...
Ethanol (C2H5OH) is a very important chemical.in addition to being widely used as an industrial solvent,a gasoline additive,and an alternative fuel,it is well known as the alcoholic beverages.A common name for ethanol is grain alcohol because it is formed by the fermentation of glucose (C6H12O6) and other sugars in grains such as corn,wheat and barley: C6H12O6---'C2H5OH + CO2 The previous reaction has been carried out for many centuries and is one of the oldest manufacturing processes.In a more recent development,ethanol...
Synthetically produced ethanol is an important industrial commodity used for various purposes, including as a solvent...
Synthetically produced ethanol is an important industrial commodity used for various purposes, including as a solvent (especially for substances intended for human contact or consumption); in coatings, inks, and personal care products; for sterilization; and as a fuel. Industrial ethanol is a petrochemical synthesized by the hydrolysis of ethylene: C2H4 (g) + H2O (v) <=>C2H5OH (v) Some of the product is converted to diethyl ether in the undesired side reaction: 2 C2H5OH (v)<=> (C2H5 )2O (v) + H2O (v) The...
How would reported income differ if LIFO rather than FIFO were used when purchase prices are...
How would reported income differ if LIFO rather than FIFO were used when purchase prices are rising? When purchase prices are falling? How would the balance sheet accounts be affected if LIFO rather than FIFO were used when purchase prices are rising? When purchase prices are falling?
1) Which of the following would increase GDP? a. More people walk to work rather than...
1) Which of the following would increase GDP? a. More people walk to work rather than drive cars. b. Consumers in rural areas switch from buying home heating oil to burning wood they collect on their own land. c. Farm families grow more for themselves than for the market. d. Neither the price nor the quantity of television sets changes, but the quality of sets improves. e. The amount spent on vacuum cleaners does not change, but quality decreases so...
why would a protein get translated into the ER rather than the cytosol ?
why would a protein get translated into the ER rather than the cytosol ?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT