Question

In: Chemistry

Volume of .010 M CoClPr3 added/mL Total Volume of Solution mL Total moles CoClPr3 added/ mols...

Volume of .010 M CoClPr3 added/mL Total Volume of Solution mL Total moles CoClPr3 added/ mols [CoClPr3]/(mols/L)
.10
.20
.30
.40
.50
.60
.70
.80
.90
1.00
1.10

The calibration plot is implemented by adding .10 mL increments of .010 M CoClPr3 to 4.00 mL of Pr in a cuvette. Calculate the given concentration, a table has been given to help with calculations.

Solutions

Expert Solution

moles = molarity x volume

molarity of solution = moles/total volume of solution

So for say 0.1 ml of 0.01M addition of CoClPr3 to 4 ml of Pr in a cuvette

moles of CoClPr3 = 0.01 x 0.0001 = 1 x 10^-6 mol

Total volume of solution = 4 + 0.1 = 4.1 ml = 0.0041 L

CoClPr3 concentration = 1 x 10^-6/0.0041 = 2.44 x 10^-4 mol/L

So we do rest of calculations following the same principle as shown above.

Table :

V 0.01 M CoClPr3(ml)       total Vol(ml)      moles of CoClPr3         CoClPr3(mol/L)

              0.1                              4.1                   1 x 10^-6                   2.44 x 10^-4

              0.2                              4.2                   2 x 10^-6                   4.76 x 10^-4

              0.3                              4.3                   3 x 10^-6                   6.98 x 10^-4

              0.4                              4.4                   4 x 10^-6                   9.10 x 10^-4

              0.5                              4.5                   5 x 10^-6                   1.11 x 10^-3

              0.6                              4.6                   6 x 10^-6                   1.30 x 10^-3

              0.7                              4.7                   7 x 10^-6                   1.49 x 10^-3

              0.8                              4.8                   8 x 10^-6                   1.67 x 10^-3

              0.9                              4.9                   9 x 10^-6                   1.84 x 10^-3

              1.0                              5.0                   1 x 10^-5                   2.00 x 10^-3

              1.1                              5.1                  1.1 x 10^-5                 2.16 x 10^-3


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