In: Chemistry
For the reaction Ti(s)+2F2(g)→TiF4(s) compute the theoretical yield of the product (in grams) for each of the following initial amounts of reactants. Part A 2.5 g Ti, 1.8 g F2 Express your answer using two significant figures. Part B 0.235 g Ti, 0.286 g F2 Express your answer using two significant figures.
A)
Molar mass of Ti = 47.87 g/mol
mass(Ti)= 2.5 g
use:
number of mol of Ti,
n = mass of Ti/molar mass of Ti
=(2.5 g)/(47.87 g/mol)
= 5.222*10^-2 mol
Molar mass of F2 = 38 g/mol
mass(F2)= 1.8 g
use:
number of mol of F2,
n = mass of F2/molar mass of F2
=(1.8 g)/(38 g/mol)
= 4.737*10^-2 mol
Balanced chemical equation is:
Ti + 2 F2 ---> TiF4
1 mol of Ti reacts with 2 mol of F2
for 5.222*10^-2 mol of Ti, 0.1044 mol of F2 is required
But we have 4.737*10^-2 mol of F2
so, F2 is limiting reagent
we will use F2 in further calculation
Molar mass of TiF4,
MM = 1*MM(Ti) + 4*MM(F)
= 1*47.87 + 4*19.0
= 123.87 g/mol
According to balanced equation
mol of TiF4 formed = (1/2)* moles of F2
= (1/2)*4.737*10^-2
= 2.368*10^-2 mol
use:
mass of TiF4 = number of mol * molar mass
= 2.368*10^-2*1.239*10^2
= 2.934 g
Answer: 2.9 g
B)
Molar mass of Ti = 47.87 g/mol
mass(Ti)= 0.235 g
use:
number of mol of Ti,
n = mass of Ti/molar mass of Ti
=(0.235 g)/(47.87 g/mol)
= 4.909*10^-3 mol
Molar mass of F2 = 38 g/mol
mass(F2)= 0.286 g
use:
number of mol of F2,
n = mass of F2/molar mass of F2
=(0.286 g)/(38 g/mol)
= 7.526*10^-3 mol
Balanced chemical equation is:
Ti + 2 F2 ---> TiF4
1 mol of Ti reacts with 2 mol of F2
for 4.909*10^-3 mol of Ti, 9.818*10^-3 mol of F2 is required
But we have 7.526*10^-3 mol of F2
so, F2 is limiting reagent
we will use F2 in further calculation
Molar mass of TiF4,
MM = 1*MM(Ti) + 4*MM(F)
= 1*47.87 + 4*19.0
= 123.87 g/mol
According to balanced equation
mol of TiF4 formed = (1/2)* moles of F2
= (1/2)*7.526*10^-3
= 3.763*10^-3 mol
use:
mass of TiF4 = number of mol * molar mass
= 3.763*10^-3*1.239*10^2
= 0.4661 g
Answer: 0.47 g