In: Chemistry
Clausisus Claperyron Problem. Find the delta H, graph and calculate the slope. Data: Temeratrue in Celcisus- 0, 20, 25, 40, 70, 100. Pressure in Torr- 4.579, 17.535, 23.756, 53.324, 233.7, 760. Plot all 6 data points.
Solution :-
To calculate the Delta H vap we need to plot a graph of the temperature and pressure
ln P vs 1/T
need to use temperaure in kelvin
Following image shows the plot
the slope of the line is the equals to the - Delta H/R
so the - delta H = slope * R
-delta H = -5199.6 * 8.314 J per mol
- delta H = -43230 J /mol
multiplying by negative sign on both side we get
delta H = 43230 J /mol
lets convert it to kJ
43230 J/mol * 1 kJ / 1000 J = 43.23 kJ/mol