In: Chemistry
Here are some questions and their answers. I would appreciate it if someone could explain to me step by step how to get the answer?
1) A student pipets 25 mL of propanoic acid from a stock container labeled 0.18 M propanoic acid. The student then dilutes the 25 mL to 100 mL with distilled water. He labels the bottle of 100 mL of propanoic acid with what concentration? The answer for this is 0.045M propanoic acid, but can someone show step by step how to get to this answer?
2) Which of the following three salts would be acidic if
dissolved in water: I. KCN II. NH4Br III. C2H5NH3Cl
answer: II and III only (how and why???)
3) What is the OH− concentration in Drano, a common drain cleaner that has a pH of 12.3 at 25oC? Answer: 0.02 M
4) What is the hydronium ion concentration (x) in a 1.23M
solution of hypochlorous acid (HOCl) at 25oC. Answer: sqrt 1.23 ∗
3.5x10^-8
5) The two acid dissociation constants for sulfurous acid, H2SO3,
are 1.3× 10–2 and 6.3× 10–8 at 25oC. The base constant, Kb, for
HSO3– is:7.7 × 10^–13
1)
we know that
for dilution
moles of solute = constant
also
moles = molarity x volume
so
M1V1 = M2V2
0.18 x 25 = M2 x 100
M2 = 0.045
so
the final concentration is 0.045 M
2)
for a salt to be acidic
it should be formed from strong acid and weak base
KCN fromed from weak acid (HCN) and strong base (KOH)
NH4Br ---> strong acid (HBr) and weak base (NH3)
C2H5NH3Cl ---> strong acid (HCl) and weak base ( C2H5NH2)
so
the answer is ll and lll
3)
we know that
pH = -log [H+]
so
12.3 = -log [ H+]
[H+] = 5 x 10-13
now
[H+] [OH-] = 10-14
so
5 x 10-13 x [OH-] = 10-14
[OH-] = 0.02 M
4) given HOCl
it is a weak acid
for weak acids
[H+] = sqrt ( Ka x C)
aslo
Ka for HOCl is 3.5 x 10-8
so
[H+] = sqrt ( 1.23 x 3.5 x 10-8)
[H+] = 2.075 x 10-4
5)
we know that
Ka x Kb = 10-14
we need Kb for HS03-
so
Ka should be for its conjugate acid H2S03
so
in tis case
Ka = Ka1 = 1.3 x 10-2
so
1.3 x 10-2 x Kb = 10-14
Kb = 7.69 x 10-13