In: Chemistry
calculate the molar enthalpy
Zn+2HCl→ZnCl2+H2 -80.7kj/mol
Zn+1/2O2→ZnO ?
ZnO(s) + H+ → H2O (l) + Zn2 +(aq) and using 1 g of solid zinc oxide (with enough acid) only gives 0.235 kJ of heat. And finally, the heat of formation of liquid water is -285.9 kJ/mol.
Find out the enthalpies of formation for all compounds involved
in the reaction using the source given in Resources. Those values
are usually given in kilojoules (kJ):
Zn = 0 kJ
HCl = -167.2 kJ
ZnCl2 = -415.1 kJ
H2 = 0 kJ
Enthalpies of formation of elements such as Zn or H2 are equal to
zero.
Add up the enthalpies of formation of the reagents of the reaction. The reagents are zinc and hydrochloric acid, and the sum is 0 + 2 * ( -167.2) = -334.3. Note that the heat of formation of HCl is multiplied by 2 because the reaction coefficient of this compound is 2.
Sum up the enthalpies of formation of the reaction products. For this reaction, products are zinc chloride and hydrogen, and the sum is -415.1 + 0 = -415.1 kJ.
Subtract the enthalpy of the reagents from the enthalpy of the products to calculate the enthalpy (heat) of the zinc reaction; the enthalpy is -415.1 - (-334.3) = -80.7 kJ.
The enthalpy of the reaction is (the sum of the enthalpy of products - the sum of the enthalpy of the reactants).
In this problem, are the products.
The enthalpy formation of any element (in this case is ) is 0 because gives zero.
Therefore, [2(-285.9)-0] - [(0.235) + (0) + (-80.7)] = -552.83 kJ.