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Sodium reacts with chlorine gas according to the reaction What volume of Cl2 gas, measured at...

Sodium reacts with chlorine gas according to the reaction What volume of Cl2 gas, measured at 867 torr and 55.0 °C, is required to form 42.0 g NaCl (58.44 g/mol)

Solutions

Expert Solution

2Na + Cl2 2NaCl

Number of moles of NaCl , n = mass/molar mass

                                          = 42.0 g / 58.44 (g/mol)

                                          = 0.719 moles

According to the above balanced equation ,

2 moles of NaCl formed from 1 mole of Cl2

0.719 moles of NaCl formed from M mole of Cl2

M = ( 1x0.719) /2

    = 0.359 moles

Calculation of volume of chlorine gas :

We know that PV = nRT

Where

T = Temperature = 55.0 oC = 55.0+273 = 328 K

P = pressure = 867 torr = 867/760 atm = 1.140 atm

n = No . of moles = 0.359 mol

R = gas constant = 0.0821 L atm / mol - K

V= Volume of the gas = ?

Plug the values we get

V = nRT / P

   = ( 0.359x0.0821x328) / 1.140

   = 8.48 L

Therefore the volume of chlorine gas is 8.48 L


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