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What is the crystal structure with the least atomic packing factor in metal?

What is the crystal structure with the least atomic packing factor in metal?

Solutions

Expert Solution

Atomic packing factor

= (atoms/unit cell) x (volume/atom) / (volume/unit cell)

For simple cubic structure

atoms/unit cell = 8 x (1/8) = 1

Volume/atom = (4/3)(0.5a)3

Volume/unit cell = a3

a = side of cube

Atomic packing factor for simple cubic

= (1) x [ (4/3)(0.5a)3] / (a3)

= 0.52

For BCC structure

atoms/unit cell = 2

Volume/atom = (4/3)()3

Volume/unit cell = a3

Atomic packing factor for BCC

= (2) x [ (4/3)()3] / (a3)

= 0.68

For FCC structure

atoms/unit cell = 4

Volume/atom = (4/3)()3

Volume/unit cell = a3

Atomic packing factor for FCC

= (4) x [ (4/3)()3] / (a3)

= 0.74

Least atomic packing factor is for the simple cubic structure


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