Question

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Which are the Brønsted–Lowry acids in the following equilibrium?Which are the Brønsted–Lowry acids in the following...

Which are the Brønsted–Lowry acids in the following equilibrium?Which are the Brønsted–Lowry acids in the following equilibrium? CH3COOH(aq) + NaOH(l)⇌ NaCH3COO(aq) + H2O(l)CH3COOH(aq) + NaOH(l)⇌ NaCH3COO(aq) + H2O(l)

Select one:

a. CH3COO–and OH––

b. H2O and OH–

c. H2O, CH3COOH, and OH–

d. CH3COO–and CH3COOH

e. H2O and CH3COOH

Solutions

Expert Solution

Ans. Given reaction: CH3COOH(aq) + NaOH(aq) ---------> NaCH3COO-(aq) + H2O

# A Bronsted-Lowery acid is a chemical species that donates a proton (H+). A Bronsted-Lowery base is a chemical species that accepts a proton (H+)

# In the given reaction, CH3COOH acts as Bronsted-Lowry acid. However, due to reaction with strong base (NaOH), all of CH3COOH would be present in form of CH3COO-. Since there is no more acid (CH3COOH) in the reaction mixture, no equilibrium of Bronsted-Lowry acid would be established.

# The conjugate base in above reaction, NaCH3COO-, would accept a proton from H2O as follow-

            NaCH3COO-(aq) + H2O(l) <--------> NaCH3COOH(aq) + OH-

In the above reaction, H2O acts as weak acid (weak Bronsted-Lowry acid) and is in equilibrium with its conjugate base OH-.

Therefore, for the given reaction, the Bronsted-Lowry acid H2O is in equilibrium with its conjugate base OH-.

# So, correct option is- B. H2O and OH-


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