Question

In: Chemistry

Use Examples 4.16 to determine the  hybridization for each central atom ( respectively C, C, O, N)in...

Use Examples 4.16 to determine the  hybridization for each central atom ( respectively C, C, O, N)in the following molecule:

CH3COONH2

Group of answer choices

sp3, sp2, sp2, sp3

sp3, sp2, sp, sp2

sp3, sp2, sp , sp3d

sp3, sp2, sp3, sp3

Solutions

Expert Solution

Answer:-

Step 1:-

Hybridisation index (I) = GA + 1/2 (VE - V - C)

Where, GA = Number of groups or atoms attached to the central atom

VE = Number of valance electrons present in the central atom

V = Valance of the central atom

C = Charge (if species is ionic)

Step 2:-

After knowing the value of I, the hybrid state is predicted as:

Value of I 2 3 4 5 6 7
Hybrid state of central atom sp sp2 sp3 sp3d sp​​​​​​​3​​​​​​​d2 sp3d3

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​​​​​​​

i) Taking *C atom as central atom:

I = 4 + 1/2 × (4 - 4 - 0) = 4 = sp3

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ii) Taking **C atom as central atom:

I = 3 + 1/2 × (4 - 4 - 0) = 3 = sp2

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iii) Taking *O atom as central atom:

I = 2 + 1/2 × (6 - 2) = 4 = sp3

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iv) Taking N atom as central atom:

I = 3 + 1/2 × (5 - 3) = 4 = sp3

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Hence , correct answer is option 4) - sp3 , sp2 , sp3 , and sp3 .


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