Question

In: Chemistry

In the structure of testosterone, identify all the primary, secondary, tertiary, and quarternary carbons.

In the structure of testosterone, identify all the primary, secondary, tertiary, and quarternary carbons.

Solutions

Expert Solution

This refers to the number of carbons DIRECTLY attached to the carbon atom in question.

For example

Primary would have only one other carbon attached to it like ethane.

C-C: The first carbon has only ONE other carbon attached to it. Regardless of which carbon you look at here, they both have only ONE OTHER carbon attached.

Secondary would have 2 OTHER carbons attached to the carbon in question such as this Propane isomer.

C
|
C-C

The Centre Carbon has 2 other carbons attached to it, One above, and one to the right. making this a secondary carbon.

Tertiary Carbon would thus have 3 other carbon attached to itas this Isopropane. And Quartinary carbon would have 4 other carbons.

Tertiary: (the dots are there to just keep the structure in place for the answer application once submited)

....C
....|
H-C-C :
....|
....C

This proprane isomer shows that the centre carbon has 3 other carbons attached thus teritary.


And a Quartianry which you didnt ask for but ill explain anyhow:

.....C
......|
..C-C-C
.....|
.....C
The centre Carbon here has 4 other carbons attached to it.

If we substitute and superimpose numbers onto the quartinary example, as follows:

.....1
..2-3-4
.....5

Number 1 representing a carbon, would be primary
Number 2 would be priary as well as there is only ONE other Carbon attached to it or number in this case.
Number 4 & 5 would be like numbers 1 and 2 as well.
Number 3 would be Quartinary.


Now if we changed the structure to tertiary as follows( the placement of the numbers dont mean anything here):

....1-5
.....|
..3-2- 4

Then Number 1 is secondary b/c the numbers 5 and 2 are attached to it.
Number 2 is tertiary becasue it has 3 other numbers to it (3,4,1)
One numbers 5,3,4 are all primary bc they only have ONE carbon DIRECTLY attached to it.


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