Question

In: Chemistry

EDTA is a hexaprotic system with the following pKa values:pKa1 = 0.00 pKa4 = 2.69 pKa2...

EDTA is a hexaprotic system with the following pKa values:pKa1 = 0.00 pKa4 = 2.69 pKa2 = 1.50 pKa5 = 6.13 pKa3 = 2.00 pKa6 = 10.37

The distribution of protonated forms of EDTA will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA, it is convenient to calculate the fraction of EDTA that is in the completely unprotonated form, Y4– (see the figure). This fraction is designated αY4–. Calculate αY4– at the following two pH values:

pH: 3.50 and pH: 10.45

Solutions

Expert Solution


Related Solutions

EDTA is a hexaprotic system with the following pKa values: pKa1 = 0.00 pKa4 = 2.69...
EDTA is a hexaprotic system with the following pKa values: pKa1 = 0.00 pKa4 = 2.69 pKa2 = 1.50 pKa5 = 6.13 pKa3 = 2.00 pKa6 = 10.37 The distribution of protonated forms of EDTA will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA, it is convenient to calculate the fraction of EDTA that is in the completely unprotonated form, Y4– . This fraction is designated αY4–. Calculate αY4– at the following two pH values: pH=3.45...
EDTA is a hexaprotic system with the p K a values: p K a1 = 0.00...
EDTA is a hexaprotic system with the p K a values: p K a1 = 0.00 , p K a2 = 1.50 , p K a3 = 2.00 , p K a4 = 2.69 , p K a5 = 6.13 , and p K a6 = 10.37 . The distribution of the various protonated forms of EDTA will therefore vary with pH. For equilibrium calculations involving metal complexes with EDTA , it is convenient to calculate the fraction of EDTA...
2) Ethylenediamine tetraacetic acid (EDTA) is a hexaprotic acid that was used as a food preservative...
2) Ethylenediamine tetraacetic acid (EDTA) is a hexaprotic acid that was used as a food preservative to prevent metal leaching in canned food before monolayer coatings were developed. Let’s say that you find an old can of spam in your grandparents kitchen from 1946, and one of the listed ingredients is EDTA. You decide to collect the fluid from the spam container and titrate it with base to determine the concentration of EDTA. Write the chemical formula for EDTA with...
Diprotonated EDTA (ethylenediaminetetraacetic acid) is hexaprotic (H6Y2+) with the following step-wise acid dissociation constants. K1  = 1.0...
Diprotonated EDTA (ethylenediaminetetraacetic acid) is hexaprotic (H6Y2+) with the following step-wise acid dissociation constants. K1  = 1.0 K2  = 3.2×10-2 K3  = 1.0×10-2 K4  = 2.0×10-3 K5  = 7.4×10-7 K6  = 4.3×10-11 a) Use these values to compute αY4- in a solution at pH 9.26. b) Now, consider the complex formation reaction: Sr2+ + Y4− ⇌ SrY2−  logKf = 8.72 What is the conditional formation constant for SrY2− at pH 9.26? c) What is the concentration of free Sr2+ in 0.050 M Na2[Sr(EDTA)] at pH 9.26?
Phosphoric acid is a triprotic acid with the following pKa values: pKa1=2.148 pKa2=7.198 pKa3=12.375 You wish...
Phosphoric acid is a triprotic acid with the following pKa values: pKa1=2.148 pKa2=7.198 pKa3=12.375 You wish to prepare 1.000 L of a 0.0200 M phosphate buffer at pH 7.720. To do this, you choose to mix the two salt forms involved in the second ionization, NaH2PO4 and Na2HPO4, in a 1.000 L volumetric flask and add water to the mark. What mass of each salt will you add to the mixture? mass NaH2PO4= ________g mass Na2HPO4= __________g What other combination...
A weak acid H3A has pKa values of 1.95 (pKa1), 3.08 (pKa2), and 9.54 (pKa3). The...
A weak acid H3A has pKa values of 1.95 (pKa1), 3.08 (pKa2), and 9.54 (pKa3). The disodium salt of that weak acid was dissolved in deionized water to make 250.0 mL of a 0.025 M solution. What was the equilibrium concentration of H2A-?
If pKa of weak acids are the following: pKa acetic acid = 4.75 pKa propionic acid...
If pKa of weak acids are the following: pKa acetic acid = 4.75 pKa propionic acid = 4.87 pKa acitric acid = 5.40 pKa of benzoic acid = 4.19 What is the order of acids with increasing acidity Determine the pH of the following A. 100 mL of benzoic acid solution 0.03M is mixed with 200 ml water B. 50 mL of sodium hydroxide solution 0.05 M is mived with 200 ml water
) Suppose you have the following reagents: Acetate (pKa = 4.76); Phosphate (pKa = 6.77); HEPES...
) Suppose you have the following reagents: Acetate (pKa = 4.76); Phosphate (pKa = 6.77); HEPES (pKa = 7.50); Bicine (pKa = 8.30) If you want to prepare a buffer at pH 7.30, which two of these would be the best buffering agents to use? Which one of these would be the poorest? explain please
What is the isoelectric point (pI) of the polypeptide given the following pKa values: alpha-COOH pka=...
What is the isoelectric point (pI) of the polypeptide given the following pKa values: alpha-COOH pka= 9.67 alpha-NH3+ pKa= 2.17 guanidium R group pKa= 12.48 carboxylic acid R group pKa= 4.25
Answer the following chemistry question: 3. (a)  The pKa for ferric ion Fe(+3) is 2.   The pKa for...
Answer the following chemistry question: 3. (a)  The pKa for ferric ion Fe(+3) is 2.   The pKa for cupric ion Cu(+2) is 9.                 Which is a stronger Bronsted acid?  Give and explain two reasons for the ten million-fold difference in their acidities b)  The Ksp for silver tarnish, that is the black Ag2S, is 10-39, one of the smallest values indicating a VERY insoluble solid.  Why is silver sulfide so insoluble?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT