In: Chemistry
sketch a diagram showing the potential energy surface for a generic sn2 reaction
SN2 indicates a
substitution, nucleophilic,
bimolecular reaction, described by the expression
rate = k
[Nu][R-LG].
This implies that the rate determining step involves an interaction
between two species, the nucleophile and the organic
substrate.
This pathway is a concerted process (single step) as shown by the
following reaction coordinate diagrams, where there is simultaneous
attack of the nucleophile and displacement of the leaving
group(x).The nucleophile attacks at the carbon with the partial
positive charge as a result of the polar s bond to the
electronegative atoms in the leaving group.Single step reactions
have no intermediates and a single transition state (TS).
In an SN2 there is simultaneous formation of the carbon-nucleophile bond and breaking of the carbon-leaving group bond, hence the reaction proceeds via a TS(transition state) in which the central C is partially bonded to five groups.