Question

In: Chemistry

What is the pH of 10ml of 0.1M NH3, with 5ml of 0.1M of HCL. kb=1.8*10^-5

What is the pH of 10ml of 0.1M NH3, with 5ml of 0.1M of HCL. kb=1.8*10^-5

Solutions

Expert Solution

             no of moles of NH3 = molarity * volume in L

                                              = 0.1*0.01   = 0.001 moles

           no of moles of HCl    = molarity * volume in L

                                             = 0.1*0.005 = 0.0005 moles

                 NH3(aq)   + HCl (aq) -------------> NH4Cl(aq)

      I           0.001       0.0005                          0

     C        -0.0005      -0.0005                         0.0005

     E         0.0005           0                                  0.0005

                Pkb   = -logkb

                         = -log1.8*10^-5

                        = 4.75

              POH   = Pkb + log[NH4Cl]/[NH3]

                        = 4.75 + log0.0005/0.0005

                       = 4.75 + log1

                      = 4.75

              PH    = 14-POH

                        = 14-4.75    = 9.25 >>>>>answer


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